Literature DB >> 30307230

A comparison of choline:urea and choline:oxalic acid deep eutectic solvents at 338 K.

Mark Gilmore1, Leila M Moura1, Adam H Turner1, Małgorzata Swadźba-Kwaśny1, Samantha K Callear2, Jade A McCune3, Oren A Scherman3, John D Holbrey1.   

Abstract

1:2 choline chloride:urea and 1:1 choline chloride:oxalic acid deep eutectic solvents are compared at 338 K using liquid-phase neutron diffraction with H/D isotopic substitution to obtain differential neutron scattering cross sections and fitting of models to the experimental data using Empirical Potential Structure Refinement. In comparison to the previously reported study of choline chloride:urea at 303 K, we observed significant weakening and lengthening of choline-OH⋯Cl- and choline-OHhydrogen-bond acceptor correlations.

Entities:  

Year:  2018        PMID: 30307230     DOI: 10.1063/1.5010246

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  1 in total

1.  Neutron Diffraction Study of Indole Solvation in Deep Eutectic Systems of Choline Chloride, Malic Acid, and Water.

Authors:  Oliver S Hammond; Ria Atri; Daniel T Bowron; Karen J Edler
Journal:  Chemistry       Date:  2022-06-13       Impact factor: 5.020

  1 in total

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