| Literature DB >> 30307106 |
Krishnamoorthy Muralirajan1, Rajesh Kancherla1, Magnus Rueping1,2.
Abstract
Oxidative dehydrogenative aromatization and selective sulfonylation reactions of N-heterocycles under visible-light photoredox catalysis were established. The mild reaction conditions make this approach an appealing and versatile strategy to functionalize/oxidize pyrrolidines whereby arylsulfonyl chlorides were identified to be both catalyst regeneration and sulfonylation reagents.Entities:
Keywords: C(sp3)-H functionalization; C3 sulfonylation; aromatization; dehydrogenation; redox chemistry
Year: 2018 PMID: 30307106 DOI: 10.1002/anie.201808427
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336