Literature DB >> 30272984

Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines.

Huaifeng Li1, Abdullah Al-Dakhil1, Daniel Lupp1, Sandeep Suryabhan Gholap1, Zhiping Lai1, Lan-Chang Liang2,3, Kuo-Wei Huang1.   

Abstract

The first example of cobalt-catalyzed selective hydrogenation of nitriles to secondary imines is reported. The results demonstrate the significantly different selectivity compared with the previously reported cobalt catalytic system during the nitrile hydrogenation. A variety of aromatic and aliphatic nitriles are hydrogenated to the corresponding secondary imines.

Entities:  

Year:  2018        PMID: 30272984     DOI: 10.1021/acs.orglett.8b02744

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Selective Carbanion-Pyridine Coordination of a Reactive P,N Ligand to RhI.

Authors:  Marc Devillard; Andreas Ehlers; Maxime A Siegler; Jarl Ivar van der Vlugt
Journal:  Chemistry       Date:  2019-02-12       Impact factor: 5.236

  1 in total

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