Literature DB >> 30270380

Local ionic liquid environment at a modified iron porphyrin catalyst enhances the electrocatalytic performance of CO2 to CO reduction in water.

Asma Khadhraoui1, Philipp Gotico, Bernard Boitrel, Winfried Leibl, Zakaria Halime, Ally Aukauloo.   

Abstract

In this study we report a strategy to attach methylimidazolium fragments as ionic liquid units on an established iron porphyrin catalyst for the selective reduction of CO2 to CO. Importantly, we found that the tetra-methylimidazolium containing porphyrin exhibits an exalted electrocatalytic activity at low overpotential in water precluding the need for an external proton donor.

Entities:  

Year:  2018        PMID： 30270380     DOI： 10.1039/c8cc06475j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Multifunctional Charge and Hydrogen-Bond Effects of Second-Sphere Imidazolium Pendants Promote Capture and Electrochemical Reduction of CO2 in Water Catalyzed by Iron Porphyrins.

Authors:  Mina R Narouz; Patricia De La Torre; Lun An; Christopher J Chang
Journal:  Angew Chem Int Ed Engl       Date:  2022-08-08       Impact factor: 16.823

Review 2.  Recent Progress in (Photo-)-Electrochemical Conversion of CO2 With Metal Porphyrinoid-Systems.

Authors:  Dženeta Dedić; Adrian Dorniak; Uwe Rinner; Wolfgang Schöfberger
Journal:  Front Chem       Date:  2021-07-16       Impact factor: 5.221

Review 3.  Immobilization strategies for porphyrin-based molecular catalysts for the electroreduction of CO2.

Authors:  Maryam Abdinejad; Keith Tang; Caitlin Dao; Saeed Saedy; Tom Burdyny
Journal:  J Mater Chem A Mater       Date:  2022-03-17

Review 4.  Homogeneous and heterogeneous molecular catalysts for electrochemical reduction of carbon dioxide.

Authors:  Maryam Abdinejad; M Nur Hossain; Heinz-Bernhard Kraatz
Journal:  RSC Adv       Date:  2020-10-15       Impact factor: 4.036

5.  Electronic structure analysis of electrochemical CO2 reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands.

Authors:  Maxime Tarrago; Shengfa Ye; Frank Neese
Journal:  Chem Sci       Date:  2022-06-29       Impact factor: 9.969

6.  Consistent inclusion of continuum solvation in energy decomposition analysis: theory and application to molecular CO2 reduction catalysts.

Authors:  Yuezhi Mao; Matthias Loipersberger; Kareesa J Kron; Jeffrey S Derrick; Christopher J Chang; Shaama Mallikarjun Sharada; Martin Head-Gordon
Journal:  Chem Sci       Date:  2020-11-27       Impact factor: 9.825
  6 in total

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