Literature DB >> 30260215

Lanthanide Tetranuclear Cage and Mononuclear Cocrystalline Nitronyl Nitroxide Complex with Single-Molecule-Magnet Behavior.

Peng Yun Chen, Ming Ze Wu, Ting Li, Xiu Juan Shi, Li Tian, Zhong Yi Liu.   

Abstract

The first tetranuclear metallacage and mononuclear cocrystalline DyIII-radical complex was synthesized and characterized. The metallacage in [Dy4(hfac)8(IMPhThio)2(OH)4][Dy(hfac)3(NITPhThio)2] consists of Dy(hfac)2+ groups bridged by OH- and the IMPhThio radical. Field-induced single-molecule-magnet behavior was observed in the nitronyl nitroxide radical-bridged polynuclear complex.

Entities:  

Year:  2018        PMID: 30260215     DOI: 10.1021/acs.inorgchem.8b01923

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  A high-nuclearity complex containing a decanuclear iron(iii)/oxo cage in a football-like structure and rare (R-/S)-hemiacetalate ligands in a butterfly-like format.

Authors:  Chunying Zheng; Mingyue Liang; Haofen Sun; Jiping Ma; Xuejun Bi; Yang Zhao; Weiqiang Tan; Hui Li
Journal:  RSC Adv       Date:  2019-12-04       Impact factor: 4.036

  1 in total

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