Literature DB >> 30256105

Realizing the Photoene Reaction with Alkenes under Visible Light Irradiation and Bypassing the Favored [2 + 2]-Photocycloaddition.

Sapna Ahuja1, Ramya Raghunathan2, Elango Kumarasamy2, Steffen Jockusch2, Jayaraman Sivaguru1.   

Abstract

The textbook photoreaction between two alkenes is the [2 + 2]-photocycloaddition resulting in functionalized cyclobutanes. Herein, we disclose an unusual reactivity of alkenes that favor photoene reaction over the [2 + 2]-photocycloaddition.

Entities:  

Year:  2018        PMID: 30256105     DOI: 10.1021/jacs.8b08100

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

1.  Keeping the name clean: [2 + 2] photocycloaddition.

Authors:  Jayaraman Sivaguru; Thorsten Bach; Vaidhyanathan Ramamurthy
Journal:  Photochem Photobiol Sci       Date:  2022-05-24       Impact factor: 4.328

2.  Alkyne-Alkene [2 + 2] cycloaddition based on visible light photocatalysis.

Authors:  Sujin Ha; Yeji Lee; Yoonna Kwak; Akash Mishra; Eunsoo Yu; Bokyeong Ryou; Cheol-Min Park
Journal:  Nat Commun       Date:  2020-05-19       Impact factor: 14.919

  2 in total

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