| Literature DB >> 30251063 |
Diganta Kumar Das1, Bidisha Bharali2, Swrangsi Goyari2.
Abstract
The condensation product (L) of 4-methoxybenzaldehyde and ethylenediamine has been synthesised and characterised. L showed a 21 times enhancement in fluorescence intensity on interaction with Ce3+ in CH3OH at λmax = 360 nm when excited with 270 nm photons. Metal ions K+, Na+, Al3+, Co2+, Hg2+, Cd2+, Ni2+, Zn2+, Mn2+, Mg2+ and Ca2+ do not interfere. The stoichiometry of binding and the binding constants were determined from spectroscopic data and found to be 1:1 and 104.8 M respectively. The detection limit was found to be 10-5.2 M. The protonation/de-protonation of water molecules coordinated to Ce3+ was found to show interesting behaviour on the fluorescence of L:Ce3+.Entities:
Keywords: 4-methoxybenzaldehyde; Cerium(III); Fluorescence; Protonation/deprotonation; Sensor
Year: 2018 PMID: 30251063 DOI: 10.1007/s10895-018-2298-0
Source DB: PubMed Journal: J Fluoresc ISSN: 1053-0509 Impact factor: 2.217