Literature DB >> 30250960

Cyanomethyl anion transfer reagents for diastereoselective Corey-Chaykovsky cyclopropanation reactions.

Renè Hommelsheim1, Katharina J Hock, Christian Schumacher, Mohanad A Hussein, Thanh V Nguyen, Rene M Koenigs.   

Abstract

A readily available and bench-stable cyanomethyl sulfonium salt was used in highly diastereoselective Corey-Chaykovsky cyclopropanation reactions of electron-poor olefins. This efficient method provides a rapid route to access densely functionalized cyclopropyl nitriles.

Entities:  

Year:  2018        PMID: 30250960     DOI: 10.1039/c8cc05602a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Catalytic Synthesis of Trifluoromethyl Cyclopropenes and Oligo-Cyclopropenes.

Authors:  Uyen P N Tran; Renè Hommelsheim; Zhen Yang; Claire Empel; Katharina J Hock; Thanh V Nguyen; René M Koenigs
Journal:  Chemistry       Date:  2020-01-20       Impact factor: 5.236

  1 in total

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