Literature DB >> 30246204

Regio- and chemoselective rearrangement of terminal epoxides into methyl alkyl and aryl ketones.

Yingying Tian1, Eva Jürgens, Doris Kunz.   

Abstract

The development of the highly active pincer-type rhodium catalyst 2 for the nucleophilic Meinwald rearrangement of functionalised terminal epoxides into methyl ketones under mild conditions is presented. An excellent regio- and chemoselectivity is obtained for the first time for aryl oxiranes.

Entities:  

Year:  2018        PMID： 30246204     DOI： 10.1039/c8cc06503a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Sustainable catalytic rearrangement of terpene-derived epoxides: towards bio-based biscarbonyl monomers.

Authors:  P S Löser; P Rauthe; M A R Meier; A Llevot
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2020-07-06       Impact factor: 4.226

2.  Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex.

Authors:  Amy E Kynman; Samantha Lau; Sean O Dowd; Tobias Krämer; Adrian B Chaplin
Journal:  Eur J Inorg Chem       Date:  2020-10-20       Impact factor: 2.524

3.  Deoxygenation of Epoxides with Carbon Monoxide.

Authors:  Theo Maulbetsch; Eva Jürgens; Doris Kunz
Journal:  Chemistry       Date:  2020-07-23       Impact factor: 5.236
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.