Binary colloidal crystals (BCCs): Interactions, fabrication, and applications.

The organization of matter into hierarchical structures is a fundamental characteristic of functional materials and living organisms. Binary colloidal crystal (BCC) systems present a diversified range of nanotopographic structures where large and small colloidal particles simultaneously self-assemble into either 2D monolayer or 3D hierarchical crystal lattices. More importantly, understanding how BCCs form opens up the possibility to fabricate more complex systems such as ternary or quaternary colloidal crystals. Monolayer BCCs can also offer the possibility to achieve surface micro- and nano-topographies with heterogeneous chemistries, which can be challenging to achieve with other traditional fabrication tools. A number of fabrication methods have been reported that enable generation of BCC structures offering high accuracy in growth with controllable stoichiometries; however, it is still a challenge to make uniform BCC structures over large surface areas. Therefore, fully understand the mechanism of binary colloidal self-assembly is crucial and new/combinational methods are needed. In this review, we summarize the recent advances in BCC fabrication using particles made of different materials, shapes, and dispersion medium. Depending on the potential application, the degree of order and efficiency of crystal formation has to be determined in order to induce variability in the intended lattice structures. The mechanisms involved in the formation of highly ordered lattice structures from binary colloidal suspensions and applications are discussed. The generation of BCCs can be controlled by manipulation of their extensive phase behavior, which facilitates a wide range potential applications in the fields of both material and biointerfacial sciences including photonics, biosensors, chromatography, antifouling surfaces, biomedical devices, and cell culture tools.