Literature DB >> 30243106

Infrared band strengths for amorphous and crystalline methyl propionate, a candidate interstellar molecule.

Reggie L Hudson1, Ella F Mullikin2.   

Abstract

Mid-infrared spectra of amorphous and crystalline methyl propionate, CH3CH2COOCH3, are presented for the first time from a single laboratory, along with measurements of the refractive index of each solid form. Density estimates are made and IR band strengths and absorption coefficients are calculated. Vapor pressures of crystalline methyl propionate at 140-150 K are reported along with an enthalpy of sublimation. Spectroscopic results are compared to a recent study of this compound, and the phase of methyl propionate in that work is identified. Several applications are described. Published by Elsevier B.V.

Entities:  

Keywords:  Amorphous solids; Astrochemistry; Band strengths; IR spectroscopy; Ices

Year:  2018        PMID: 30243106     DOI: 10.1016/j.saa.2018.09.032

Source DB:  PubMed          Journal:  Spectrochim Acta A Mol Biomol Spectrosc        ISSN: 1386-1425            Impact factor:   4.098


  3 in total

1.  Quantifying acetaldehyde in astronomical ices and laboratory analogues: IR spectra, intensities, 13C shifts, and radiation chemistry.

Authors:  Reggie L Hudson; Robert F Ferrante
Journal:  Mon Not R Astron Soc       Date:  2019-12-11       Impact factor: 5.287

2.  Testing Densities and Refractive Indices of Extraterrestrial Ice Components Using Molecular Structures - Organic Compounds and Molar Refractions.

Authors:  Reggie L Hudson; Mark J Loeffler; Robert F Ferrante; Perry A Gerakines; Falvia M Coleman
Journal:  Astrophys J       Date:  2020-02-28       Impact factor: 5.874

3.  Infrared intensities and molar refraction of amorphous dimethyl carbonate - comparisons to four interstellar molecules.

Authors:  Reggie L Hudson; Falvia M Coleman
Journal:  Phys Chem Chem Phys       Date:  2019-05-20       Impact factor: 3.676

  3 in total

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