Synthesis and Irreversible Thermochromic Sensor Applications of Manganese Violet.

An irreversible thermochromic material based on manganese violet (MnNH₄P₂O₇) is synthesized. The crystal phase, chemical composition, and morphology of the synthesized material are analyzed using X-ray diffraction, scanning electron microscopy coupled with energy-dispersive X-ray spectrometry, and Fourier-transform infrared spectroscopy. The absorption spectra of the synthesized material are obtained using a UV-Vis spectrometer, and the thermochromism exhibited by the powdered samples at high temperatures is also investigated. The as-synthesized manganese violet pigment consists of pure α-MnNH₄P₂O₇ phase. In addition, the synthesized pigment largely consists of hexagonal crystals with a diameter of hundreds of nanometers. On heating, the pigment simultaneously loses H₂O and NH₃ in two successive steps at approximately 330⁻434.4 °C and 434.4⁻527 °C, which correspond to the formation of an intermediate phase and of Mn₂P₄O12, respectively. An overall mass loss of 14.22% is observed, which is consistent with the expected 13.79%. An irreversible color change from violet to white is observed after exposure of the synthesized manganese violet pigment at 400 °C for 30 min. This is attributed to the oxidation of ammonia to hydroxylamine, which then decomposes to nitrogen and water, or alternatively to the direct oxidation of ammonia to nitrogen. Furthermore, we demonstrate the potential application of synthesized manganese violet in the production of irreversible thermochromic paint by mixing with potassium silicate solution as a binder and deionized water as a solvent at a specific ratio. The thermochromic paint is then applied in fabrication of irreversible thermochromic sensors by coating it onto a steel plate surface. Finally, we show that manganese violet-based irreversible thermochromic sensors are able to detect temperatures around 400 °C by changing color from violet to white/milky.

1. Introduction

Thermochromic materials are currently receiving considerable attention due to their applications in life sciences [1,2], in flow sensing [3,4,5], as well as their potential applications as temperature sensors in a wide range of devices, such as aeronautical [6,7,8] and gas tun class="Chemical">rbinpan>e enpan>ginpan>e componenpan>ts [9], household applianpan>ces [10], hotplates anpan>d furnpan>aces [11]. Thermochromic materials canpan> be divided inpan>to reversible anpan>d irreversible types. The first exhibit a reversible color chanpan>ge followinpan>g a temperature variation. The chanpan>ge inpan> color canpan> be reversed through heatinpan>g–coolinpan>g cycles, whereinpan> the material regainpan>s its originpan>al color after coolinpan>g [12]. Inpan> contrast, irreversible thermochromic materials exhibit anpan> irreversible color chanpan>ge based on the peak temperature of the surrounpan>dinpan>g enpan>vironmenpan>t. The chanpan>ge inpan> color canpan>not be reversed upon coolinpan>g, thus providinpan>g permanpan>enpan>t records that canpan> be visualized offlinpan>e [7]. Irreversible color chanpan>ges over a wide ranpan>ge of temperatures canpan> be obtainpan>ed by the decomposition of irreversible thermochromic materials such as pan> class="Chemical">phosphates, carbonates, and hydroxides [11]. The final color of the irreversible thermochromic material is dependent on both the temperature it is subjected to and the time period over which it is held at a high temperature [9]. Table 1 shows a list of various irreversible thermochromic materials which can change color under different temperatures.

Table 1

Thermochromic materials, their reversible (↔) or irreversible (→) color change, and transition temperatures [13].

Thermochromic Materials	Color Change	Transition Temperature (°C)
[NH2(C2H5)2]2CuCl4	deep green ↔ yellow	38
Ag2(HgI4)	yellow ↔ orange	50
CuI	gray-tan → orange	60–62
Cu2(HgI4)	red ↔ brown	70
HgI2	red ↔ yellow	127
2Cu(CNS)2·2pyridine	green → yellow	135
	yellow → black	220
NH4VO3	white → brown	150
	brown → black	170
CoCO2	violet → black	330
MnNH4P2O7	violet → white	400
NiC2O4	light blue → black	410

There are many techniques which can be used for surface temperature measurement. Thermocouples are fixed on components during temperature measurements [7]. Their main advantage is to provide very accurate measurements. Hence, they can be used as a valuable means of local validation of the surface temperature. Optic sensors based on fiber Bragg grating technology are another technique for surface temperature measurement. The main advantage of this technique is to give very accurate temperature measurements. However, these measurement techniques only give temperature information at disn class="Chemical">crete poinpan>ts, anpan>d n class="Chemical">critical hot spots may be missed [7]. Irreversible thermochromic paints are global measurement techniques which give the surface temperature distribution with a high spatial resolution. They can be applied to the most complex surface shapes, and do not interfere with the thermal behavior of the component, as the layer thickness does not exceed 40 μm [7].

Manganese violet (pan> class="Chemical">MV, with empirical formula NH4MnP2O7) has been approved for use in a number of important pigment applications, including cosmetics, toys, and plastics [14]. Moreover, the color of this compound changes from violet to white upon heating [13]. In particular, on gentle heating, the color of MV powder reversibly changes from violet to blue because of the loss of water. The original color is restored after cooling in air. Heating to higher temperatures liberates ammonia leaving a white residue, and this color change is irreversible [15].

The first synthesis of n class="Chemical">MV was reported by Lee anpan>d Brownpan>e inpan> 1968 [15]; later, the compounpan>d was synpan>thesized by Begum anpan>d Wright inpan> 2012 to study its detailed structural anpan>d physical properties [14]. However, no previous studies have inpan>vestigated the application of pan> class="Chemical">MV in irreversible thermochromic sensors. Additionally, no previous studies have used MV in its reversible range to sense temperature. Therefore, in this study MV powder was prepared to analyze its structural, physical, and thermal properties. The X-ray diffraction (XRD) result revealed the occurrence of pure α-NH4MnP2O7, which was consistent with that of the previous study [14]. The UV-Vis spectrum showed a strong, broad peak at 545 nm, which was due to the 5Eg → 5T2g transition. The thermogravimetry-differential thermal analysis (TGA-DTA) result indicated that an apparent mass loss of both H2O and NH3 occurred in two successive steps at ~330–434 °C and ~434–527 °C, which agreed well with that of the previous study [14]. Moreover, the synthesized MV powder showed the ability to irreversibly change its color from violet to white upon exposure at around 400 °C for 30 min. The obtained MV pigment was first used to produce irreversible thermochromic paint by mixing with potassium silicate solution as a binder and deionized water as a solvent at a specific ratio. The thermochromic paint was then applied in fabrication of irreversible thermochromic sensors by coating it onto a steel plate surface. These irreversible thermochromic sensors also showed an irreversible color modification from violet to white after exposure at 400 °C for 30 min. This finding highlights the potential applications of MV-based irreversible thermochromic sensors not only for detecting the temperature of engine components, household appliances, furnaces, or high-temperature ovens, but also for the rapid evaluation of the peak temperature of steel bridges or infrastructures after exposure to fire.

2. Materials and Methods

2.1. Synthesis

n class="Chemical">Manganese dioxide (pan> class="Chemical">MnO2, Sigma-Aldrich, St. Louis, MO, USA) was mixed with ammonium dihydrogen phosphate (NH4H2PO4, Sigma-Aldrich, Tokyo, Japan) and phosphoric acid (H3PO4, 85.5 wt% in H2O, Sigma-Aldrich, Buchs, Switzerland). As the phase of MnO2 does not affect the final product, we can use MnO2 with any phase for synthesis of MV. The above mixture was heated and stirred on a hot plate at 120 °C for 30 min, and then at 220 °C for a further 2 h. Excess hot water was added to the hot material, and the aqueous suspension was boiled for another 30 min. The product was washed with hot water several times and recovered via vacuum filtration. The synthesized MV powder was dried at 110 °C overnight, and then hand-ground using a pestle in an agate mortar for 30 min. This process yielded a deep violet microcrystalline powder. The synthesis procedure is summarized in Figure 1. Various synthesis conditions were explored, including different reagent ratios, reaction temperatures, and reaction times. It was found that the MV compound could be synthesized by heating and stirring the above reagents, in a Mn–NH4–P molar ratio of 1:3:4, up to 220 °C for 2 h.

Figure 1

Flow chart for the preparation of manganese violet.

2.2. Characterization Techniques

Power X-ray diffraction (XRD) analysis of the synthesized powder samples was performed on a Rigaku MiniFlex600 diffractometer (Osaka, Japan) with Cu Kα radiation. The powder patterns were recorded at room temperature in a 2θ range from 20 to 50°, with an angular step of 0.02°, and a scanning rate of 2°/min. An external SI standard was used to calibrate the instrument.

The microstructure of the synthesized samples was inpan>spected usinpan>g scanpan>ninpan>g electron mipan> class="Chemical">croscopy (SEM, SUPRATM 25, Zeiss, Jena, Germany) coupled with energy-dispersive X-ray spectrometry (EDX, X-MAXN (80 mm), Oxford, UK). The powdered samples for microstructural analysis were placed on an aluminum holder and subsequently coated with platinum.

The Fourier-transform infrared (FT-IR) spectra of the samples were characterized by a Nicolet IS5 spectrometer (Thermo Fisher Scientific, Waltham, MA, USA). The specimens were prepared by mixinpan>g the powdered samples with dried pan> class="Chemical">KBr powder, followed by the application of a force of approximately 25 MPa to form pellets. The spectra were collected over a spectral range of 3600–400 cm−1.

The thermal properties of the synthesized powder samples were analyzed by thermogravimetry-differential thermal analysis (n class="Chemical">TG-DTA, pan> class="Disease">Setaram Setsys Evolution TMA, Caluire, France). The measurements were carried out with milligram-size (10–15 mg) samples in a nitrogen environment, from room temperature to 800 °C, and with a heating rate of 5 °C/min. Variable temperature XRD measurements were also carried out on a Rigaku MiniFlex600 diffractometer with Cu Kα radiation. The samples were prepared by heating to various temperatures from 380 to 420 °C at a rate of 20 °C/min, and maintained at each temperature for 30 min.

The absorption spectra of the samples were obtained using a Konica-Minolta CM-3600d spectrophotometer (Konica Minolta, Osaka, Japan) in a wavelength range from 360 to 740 nm.

The thermochromic color changes of synthesized n class="Chemical">MV at high temperature were inpan>vestigated by addinpan>g the powdered samples inpan>to 5-mL combustion boats, followed by heatinpan>g to differenpan>t temperatures from 380 to 420 °C inpan> 10 °C steps inpan> a digital muffle furnpan>ace (FX-05, DAIHApan> class="Chemical">N Scientific, Wonju, Korea), and maintaining each temperature for 0, 5, 15, 30, and 60 min. After keeping the powdered samples at different temperatures for different periods, the combustion boats were removed and allowed to cool to room temperature, and the color change of the powder samples was recorded using a digital camera (Canon EOS 100D, Tokyo, Japan)

2.3. Thermochromic Sensor Fabrication

Irreversible thermochromic sensors were fabricated by coating a thermochromic paint onto the surface of a steel plate substrate (60 × 60 × 2 mm3). The paint was produced by mixing the synthesized n class="Chemical">MV pigmenpan>t with pan> class="Chemical">potassium silicate solution (K2SiO3, Kanto Chemical, Tokyo, Japan) as a binder and deionized (DI) water as a solvent. The paint was then coated onto the surface of the steel plate specimens using a brush. To improve the cohesion between the coating and the steel plate surface, the latter was roughened by abrasive powder treatment using a sandblasting machine [10]. After air-drying, the coated specimens were stoved in an oven at 300 °C for 1 h to fabricate the thermochromic sensors. Stoving is required to bond the paint film to the substrate; otherwise, the film would have poor toughness and could be easily damaged by handling [16]. Photographs of the steel plate specimens before and after coating are shown in Figure 2a,b. The average thickness of the coating is about 100 µm.

Figure 2

Steel plate specimens before (a) and after (b) coating.

3. Results and Discussion

3.1. Structure and Properties of Manganese Violet

3.1.1. X-ray Diffraction Spectra

Figure 3 shows the XRD patterns of our synthesized n class="Chemical">MV compounpan>d (above) anpan>d stanpan>dard PDF2 patternpan> (below). Our XRD result agrees well with the patternpan> of PDF2 Card No.: 00-021-0030. The result also reveals the occurrence of the pure α-MnNH4P2O7 phase in the sample. Recently, Anselmi et al. used the PDF2 database in combination with Rietveld refinement analysis to identify the phase composition of a commercial MV sample obtained from Kremer (45350, Aichstetten, Germany) [17]. However, it was not possible to carry out phase identification of manganese violet by means of the PDF2 database. The XRD analysis revealed that α-MnNH4P2O7 was the most abundant phase in the sample, even though very small amounts of the β-MnNH4P2O7 and kaolinite (Al2Si2O5(OH)4) phases were also observed. Moreover, the weight composition of the examined compound was estimated by Rietveld analysis as 79.9% α-MnNH4P2O7, 4.5% β-MnNH4P2O7, 13.3% kaolinite, and 2.3% stewartite (MnFe2(PO4)2(OH)2·8H2O) [17]. In another study, Begum et al. determined the crystal structure of synthesized MV from Rietveld refinement of neutron powder diffraction data [14]. The refinement analysis confirmed the occurrence of the pure α-MnNH4P2O7 phase in the samples. α-MnNH4P2O7 has a type I pyrophosphate structure, which can be described as a three-dimensional network of MnO6 octahedra corner-linked to five P2O7 units [14]. The XRD result in our study agrees well with that of the previous one [14]. Moreover, it is different from the phase composition of a commercial MV sample obtained from Kremer (45350, Aichstetten, Germany), which contains α-MnNH4P2O7 as the most abundant phase, and very small amounts of the β-MnNH4P2O7 and kaolinite phases; the XRD pattern of our synthesized MV compound reveals the occurrence of pure α-MnNH4P2O7 phase in the sample.

Figure 3

X-Ray Diffraction (XRD) patterns of synthesized manganese violet (above) and standard PDF2 pattern (below).

3.1.2. SEM and Spot-Chemical Analysis

Figure 4a and Figure S1 (Supplementary Materials) illustrate the min class="Chemical">crostructure of the as-prepared pan> class="Chemical">MV powder. The SEM micrographs clearly show that the synthesized MV pigment largely consisted of hexagonal crystals with a diameter of hundreds of nanometers. The random spot-chemical EDX analysis confirmed the presence of four main elements in the system (Figure 4b). The inset table in the figure shows the elemental content of the synthesized sample. The mass contents of O, P, Mn, and N were 46.4%, 25.0%, 22.1%, and 6.4%, respectively, while the corresponding mass contents of Mn3+, NH4+, and P2O74− were 22.1%, 8.23%, and 70.16%, respectively. However, the above contents of O, P, Mn, and N, are probably not accurate due to the errors in oxygen and nitrogen determination.

Figure 4

(a) SEM micrograph and (b) EDX analysis of synthesized manganese violet.

3.2.3. FT-IR Spectra

Figure 5 shows the FT-IR spectrum of the synthesized MV powder, which highlights several inpan>terestinpan>g features. Broad banpan>ds inpan> the 3310–2840 cm−1 region correspond to the stretchinpan>g vibrations of both pan> class="Chemical">H2O molecules and NH4+ ions [18,19,20]; the band broadening can be attributed to hydrogen bonding within the crystal [21]. The bands in the 1757–1629 cm−1 region correspond to the bending vibrations of H2O and NH4+ ions. The bending vibration of NH4+ is also observed in the 1450–1408 cm−1 range [18,22]. The asymmetric and symmetric terminal stretching vibrations of PO3 groups usually occur in the 1249–1001 cm−1 region [23]. The two peaks at 906 cm−1 and 761 cm−1 are attributed to the vibrations of P–O–P bridges [18], whereas the bands in the 630–534 cm−1 region are due to the vibrations of the diphosphate groups. This result, together with XRD and SEM-EDX results, demonstrated the formation of α-MnNH4P2O7 pigment.

Figure 5

Fourier-transform infrared (FT-IR) spectrum of synthesized manganese violet.

3.2. Thermal Properties

The XRD pattern of thermal annealing samples (Figure 6) showed that α-n class="Chemical">MnNH4P2O7 beganpan> to lose pan> class="Chemical">crystallinity at 380 °C, with extra peaks evident in the diffraction pattern. From 400 °C, crystalline α-MnNH4P2O7 was lost, leaving an unidentified poorly crystalline material up to 420 °C. The disappearance of peaks around 22° and 37.4°, together with the suppression of peak around 30.7°, demonstrated the thermal decomposition of α-MnNH4P2O7. On the other hand, the appearance of a peak around 24.9° indicated the formation of an intermediate phase, and of Mn2P4O12 [14].

Figure 6

Variable temperature XRD of α-MnNH4P2O7.

The n class="Gene">TGA-pan> class="Chemical">DTA plot given in Figure 7 indicated that an apparent mass loss of both H2O and NH3 occurred in two successive steps at ~330–434.4 °C and 434.4–527 °C, which corresponds to the formation of an intermediate phase and of Mn2P4O12, respectively [14,15]. An overall mass loss of 14.22% was observed, which is consistent with the expected 13.79%. Lee and co-workers analyzed the thermal decomposition of synthesized MV using a Stanton recording thermobalance [15]. They found that the decomposition of MnNH4P2O7 proceeded in two stages. The first stage occurred between 150 and 340 °C, and corresponded to the formation of the Mn2P4O13(NH3)2 compound (blue color). A mass loss of about 3% of the total weight was observed, reflecting the evaporation of water. This compound and its blue color are unstable. On cooling in air, it absorbs water from the air and restores the original violet color. The second stage occurred between 340 and 460 °C, corresponding to the formation of a manganous tetrametaphosphate compound (Mn2P4O12, white color). In this stage, a very sharp mass loss of 10% of the total weight was observed, due to the oxidation of ammonia to hydroxylamine, which then decomposed to nitrogen and water [15]. In another study, Begum and coworkers studied the thermal stability of synthesized MnNH4P2O7 using thermogravimetric analysis/mass spectrometry (TGA-MS). They found that simultaneous mass loss of H2O and NH3 occurred in two successive steps, at approximately 340–436 °C and then 436–520 °C, which correspond to the formation of an intermediate phase and of Mn2P4O12, respectively [14].

Figure 7

TGA-DTA plot of synthesized manganese violet.

3.3. UV-Vis Spectra

The structure of n class="Chemical">MnNH4P2O7 canpan> be desn class="Chemical">cribed as a three-dimensional network of MnO6 octahedra corner-linked to five P2O7 units, in which Mn3+ exists as a high-spin d4 ion; in a regular octahedral coordination environment, this ion would be expected to exhibit an absorbance band in the visible region due to the 5Eg → 5T2g transition. Figure 8 shows the absorbance spectrum of synthesized MV samples. The electronic spectrum shows a strong, broad peak at 545 nm, which is consistent with previous data [14,24].

Figure 8

UV-Vis spectrum of synthesized manganese violet.

3.4. Thermochromism of Synthesized Pigment Powders

After synthesizing the n class="Chemical">MV pigmenpan>t anpan>d anpan>alyzinpan>g its structural properties, the thermochromism of the synpan>thesized powders was also studied. As discussed inpan> the Experimenpan>tal section, the thermochromic color chanpan>ge of the synpan>thesized samples at high temperature was inpan>vestigated by placinpan>g the powdered samples inpan>to 5-mL combustion boats. Subsequenpan>tly, the samples were heated to differenpan>t temperatures inpan> a digital muffle furnpan>ace at a rate of 20 °C/minpan>, anpan>d mainpan>tainpan>ed at each temperature for 0, 5, 15, 30, anpan>d 60 minpan>. After exposinpan>g the powdered samples to differenpan>t temperatures for differenpan>t periods, the combustion boats were removed anpan>d allowed to cool to room temperature for 1 h, while recordinpan>g the color at specific time poinpan>ts. The results are shownpan> inpan> Figure 9. At 380 °C, the color chanpan>ge of the powdered samples was not clear anpan>d pan> class="Disease">insufficient to be observed by the naked eye, regardless of the exposure time. At 390 °C, the color of MV changed from violet to light pink after exposure for 60 min. At 400 °C, the color of MV started changing from violet to light pink after exposure for 15 min, and completely changed to white after exposure for 30 min. At 420 °C, the color of MV completely changed from violet to white after only 15 min of exposure time. This is due to the higher speed of oxidation and decomposition at higher temperature. No further color changes were observed, even after increasing the exposure time to 60 min. After cooling to room temperature, the powdered samples remained white in color, and did not recover their original color. This demonstrated that the color of MV changes from violet to white upon exposure at around 400 °C for 30 min, and this color change is irreversible. The color change at high temperature can be attributed to the oxidation of ammonia to hydroxylamine, which then decomposes to nitrogen and water, or alternatively to the direct oxidation of ammonia to nitrogen [10]. After oxidation followed by decomposition, the chemical formula of MV changes from MnNH4P2O7 to Mn2P4O12. The resulting material is not able to recover its original structure after cooling. This effect can explain the irreversible color change properties of the MV compound.

Figure 9

Color of synthesized manganese violet samples exposed at different temperatures for different periods after cooling.

3.5. Manganese Violet-Based Irreversible Thermochromic Sensors

Irreversible thermochromic sensors were fabricated by coating a n class="Chemical">MV-based thermochromic painpan>t onto a steel plate substrate. After dryinpan>g, the adhesion anpan>d resistanpan>ce to abrasion of the painpan>t film were tested by scratching on the dried surface with a finger. Various mixing conditions were explored, including different reagent ratios and stirring times. It was found that the best thermochromic paint, with excellent adhesion and resistance to abrasion, could be obtained by mixing and stirring the reagents in a MV pigment–potassium silicate–DI water weight ratio of 40:5:55, at room temperature for 30 min. Briefly, 40 g of synthesized MV was mixed with 5 g of potassium silicate solution and 55 g of DI water. The mixture was vigorously stirred for 30 min at room temperature. The resulting paint was then deposited onto the treated steel plate surface with a brush, and then dried. A second layer of the resulting paint was then deposited onto the first dried layer, and then dried. In order to elucidate the relationship between color and temperature, the sensor plates were individually heated to different temperatures in a digital muffle furnace, and maintained at each temperature for 0, 5, 15, 30, and 60 min. The process was repeated for a number of samples at different temperatures, to cover the whole measurement range from 380 to 420 °C in 10 °C steps. The color change of the sensor plates was recorded after cooling to room temperature using a digital camera (Canon EOS 100D). Figure 10 shows the color changes observed for the sensor samples at different temperatures for different periods. The original color of the sensor was violet, and started to change to light pink after exposure at 380 or 390 °C for 60 min. At 400 °C, the color of the sensor plate completely changed to white/milky after exposure for 30 min. At higher temperature (e.g., 420 °C), the color change of MV occurred faster due to the higher speed of oxidation and decomposition. No further color changes were observed, even after increasing the exposure time to 60 min. After cooling to room temperature, the sensor samples remained white and did not recover the original violet color. This demonstrated that the color of the sensor changes from violet to white/milky upon exposure at around 400 °C for 30 min, and this color change is irreversible. In thermochromic paints, the pigments are responsible for the thermochromic properties of the coating, while the binder facilitates the cohesion between the pigment particles, and the solvent helps in dissolving the binders and dispersing the pigments [7]. Thus, the color change of the present thermochromic sensor at high temperature can be attributed to the decomposition of the MV pigment, resulting in the formation of a new compound in the paint. At high temperature, the ammonia component of the MV pigment (MnNH4P2O7) is oxidized to hydroxylamine, which then decomposes to nitrogen and water, resulting in the formation of Mn2P4O12 [15]. This causes the irreversible color change of the MV pigment. This finding demonstrates that the visible color change of MV from violet to white/milky is irreversible and occurs around 400 °C, suggesting that the synthesized MV material could be applied in irreversible thermochromic sensors to monitor temperature changes around 400 °C.

Figure 10

Color changes of sensor samples exposed at different temperatures for different periods after cooling.

4. Conclusions

In summary, we have successfully synthesized and characterized the structure and properties of the n class="Chemical">MV pigmenpan>t. The as-synpan>thesized pigmenpan>t consists of pure α-pan> class="Chemical">MnNH4P2O7 phase and rod-shaped crystals with a diameter of hundreds of nanometers. On heating, the pigment simultaneously loses H2O and NH3 in two successive steps at approximately 330–434.4 °C and 434.4–527 °C. An irreversible color change of the synthesized MV pigment from violet to white/milky is observed after exposure to 400 °C for 30 min. In addition, the observed thermal behavior of a MV-based thermochromic sensor highlights the potential of this system for temperature sensing applications. This study shows that the synthesized MV pigments are promising smart materials for applications in irreversible thermochromic sensors, not only to detect the temperature of engine components, household appliances, furnaces, or high temperature ovens, but also for the rapid evaluation of the peak temperature of steel bridges or infrastructures after exposure to fire.