Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Photoinduced Palladium-Catalyzed Negishi Cross-Couplings Enabled by the Visible-Light Absorption of Palladium-Zinc Complexes.

Literature DB >> 30198144

Photoinduced Palladium-Catalyzed Negishi Cross-Couplings Enabled by the Visible-Light Absorption of Palladium-Zinc Complexes.

Irini Abdiaj¹, Lena Huck¹, José Miguel Mateo², Antonio de la Hoz², M Victoria Gomez³, Angel Díaz-Ortiz², Jesús Alcázar¹.

Abstract

A visible-light-induced Negishi cross-coupling is enabled by the activation of a Pd0 -Zn complex. With this photocatalytic method, the scope of deactivated aryl halides that can be employed in the Negishi coupling was significantly expanded. NMR experiments conducted in the presence and absence of light confirmed that the formation of the palladium-zinc complex is key for accelerating the oxidative addition step.

Entities: Chemical

Keywords: Negishi coupling; cross-coupling; flow chemistry; palladium catalysis; photocatalysis

Year: 2018 PMID： 30198144 DOI： 10.1002/anie.201808654

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

7 in total

1. Organometallic catalysis under visible light activation: benefits and preliminary rationales.

Authors: Omar Sadek; Mehdi Abdellaoui; Alexandre Millanvois; Cyril Ollivier; Louis Fensterbank
Journal: Photochem Photobiol Sci Date: 2022-02-26 Impact factor: 3.982

Review 2. Visible Light-Induced Transition Metal Catalysis.

Authors: Kelvin Pak Shing Cheung; Sumon Sarkar; Vladimir Gevorgyan
Journal: Chem Rev Date: 2021-10-08 Impact factor: 72.087

3. Visible-Light-Promoted Iron-Catalyzed C(sp² )-C(sp³ ) Kumada Cross-Coupling in Flow.

Authors: Xiao-Jing Wei; Irini Abdiaj; Carlo Sambiagio; Chenfei Li; Eli Zysman-Colman; Jesús Alcázar; Timothy Noël
Journal: Angew Chem Int Ed Engl Date: 2019-07-11 Impact factor: 15.336

4. Bio-Based (Chitosan-ZnO) Nanocomposite: Synthesis, Characterization, and Its Use as Recyclable, Ecofriendly Biocatalyst for Synthesis of Thiazoles Tethered Azo Groups.

Authors: Ali H Bashal; Sayed M Riyadh; Walaa Alharbi; Khadijah H Alharbi; Thoraya A Farghaly; Khaled D Khalil
Journal: Polymers (Basel) Date: 2022-01-19 Impact factor: 4.329

Photoinduced Palladium-Catalyzed Negishi Cross-Couplings Enabled by the Visible-Light Absorption of Palladium-Zinc Complexes.

1. Organometallic catalysis under visible light activation: benefits and preliminary rationales.

Review 2. Visible Light-Induced Transition Metal Catalysis.

3. Visible-Light-Promoted Iron-Catalyzed C(sp² )-C(sp³ ) Kumada Cross-Coupling in Flow.

4. Bio-Based (Chitosan-ZnO) Nanocomposite: Synthesis, Characterization, and Its Use as Recyclable, Ecofriendly Biocatalyst for Synthesis of Thiazoles Tethered Azo Groups.

5. A photoredox catalysed Heck reaction via hole transfer from a Ru(ii)-bis(terpyridine) complex to graphene oxide.

6. Three-component three-bond forming cascade via palladium photoredox catalysis.

7. Photocatalytic acyl azolium-promoted alkoxycarbonylation of trifluoroborates.

Photoinduced Palladium-Catalyzed Negishi Cross-Couplings Enabled by the Visible-Light Absorption of Palladium-Zinc Complexes.

1. Organometallic catalysis under visible light activation: benefits and preliminary rationales.

Review 2. Visible Light-Induced Transition Metal Catalysis.

3. Visible-Light-Promoted Iron-Catalyzed C(sp2 )-C(sp3 ) Kumada Cross-Coupling in Flow.

4. Bio-Based (Chitosan-ZnO) Nanocomposite: Synthesis, Characterization, and Its Use as Recyclable, Ecofriendly Biocatalyst for Synthesis of Thiazoles Tethered Azo Groups.

5. A photoredox catalysed Heck reaction via hole transfer from a Ru(ii)-bis(terpyridine) complex to graphene oxide.

6. Three-component three-bond forming cascade via palladium photoredox catalysis.

7. Photocatalytic acyl azolium-promoted alkoxycarbonylation of trifluoroborates.

3. Visible-Light-Promoted Iron-Catalyzed C(sp² )-C(sp³ ) Kumada Cross-Coupling in Flow.