| Literature DB >> 30188137 |
Embarek Alwedi1, J Armando Lujan-Montelongo1, Bhaskar R Pitta1, Allen Chao1, Rodrigo Cortés-Mejía1, Jorge M Del Campo1, Fraser F Fleming1.
Abstract
Asmic addresses the long-standing challenge of alkylating isocyanides, providing access to isocyanides with diverse substitution patterns. The o-anisylsulfanyl group serves a critical dual role by facilitating deprotonation-alkylation and providing a latent nucleophilic site through an unusual arylsulfanyl-lithium exchange.Entities:
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Year: 2018 PMID： 30188137 PMCID： PMC6172042 DOI： 10.1021/acs.orglett.8b02574
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005