Tetranuclear Iridium Complex with a Self-Host Feature for High-Efficiency Nondoped Phosphorescent Organic Light-Emitting Diodes.

A tetranuclear Ir complex 3IrB-IrG was newly designed and synthesized with one green-emitting complex as the core, whose periphery is encapsulated by three blue-emitting complexes via a nonconjugated linkage. In the case of such a multinuclear system, a self-host feature can be formed, showing negligible electron communication, efficient outside-in energy transfer, and unique shielding effect. When using 3IrB-IrG as the emitting layer in the absence of host, the corresponding nondoped device reveals a state-of-art luminous efficiency of 32.6 cd/A (34.2 lm/W, 9.7%) as well as CIE coordinates of (0.38, 0.58). The performance significantly outperforms that of the bare mononuclear complex IrG (8.4 cd/A, 9.2 lm/W, 2.5%), highlighting the potential of self-host multinuclear complexes to realize high-efficiency nondoped PhOLEDs for the first time.