| Literature DB >> 30160817 |
Shunsuke Einaru1, Kenta Shitamichi1, Tagui Nagano1, Akira Matsumoto1, Keisuke Asano1, Seijiro Matsubara1.
Abstract
The strained olefins in trans-cyclooctenes serve as efficient catalysts for halolactonizations, including bromolactonizations and iodolactonizations. The trans-cyclooctene framework is essential for excellent catalytic performance, and the substituents also play important roles in determining efficiency. These results are the first demonstration of catalysis by a trans-cyclooctene.Entities:
Keywords: Lewis base; halolactonization; organocatalyst; strained olefins; trans-cyclooctene
Year: 2018 PMID： 30160817 DOI： 10.1002/anie.201808320
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336