Sensitive, reproducible, and stable 3D plasmonic hybrids with bilayer WS2 as nanospacer for SERS analysis.

The highly enhanced local electromagnetic field occurring through nanometer gap between the plamonic nanostructures provides the dominant contribution in surface enhancement Raman scattering (SERS) enhancement. Thence, we designed the remarkable SERS platform (AuNPs/WS2@AuNPs hybrids) by introducing bilayer WS2 film as the precise nanospacer. Bilayer WS2 film can realize the facile and tight combination with AuNPs via the thermal decomposition approach. Dense three-dimension (3D) hot spots provided by this hybrid plasmonic nanostructures are responsible for the extremely satisfying SERS performances. Using rhodamine 6G (R6G) as the probe molecules, the AuNPs/WS2@AuNPs hybrids perform the excellent sensitivity with the minimum detectable concentration as low as 10-11 M. Uniform and reproducible SERS signals illustrate that the synthesized SERS hybrids perform the splendid spot-to-spot reproducibility (RSD~5.4%) and substrate-to-substrate reproducibility (RSD~5.7%). The stability of AuNPs and the protection of WS2 film endow this hybrid plasmonic nanostructures with the brilliant anti-oxidation stability. Moreover, the enhanced electric field distribution simulated with the COMSOL software proves the remarkable SERS performance in theory. Therefore, AuNPs/WS2@AuNPs substrate not only widens the SERS research filed of WS2, but also shows vast potential as excellent SERS sensor for practical applicability.