Literature DB >> 30124698

Bisphosphine phenol and phenolate complexes of Mn(i): manganese(i) catalyzed Tishchenko reaction.

Karthika J Kadassery1, Samantha N MacMillan, David C Lacy.   

Abstract

We synthesized new organomanganese complexes using the phenolic "pincer" type ligand H-POP. The coordination chemistry of H-POP with Mn(i) was explored, revealing a wide range of binding motifs. Finally, we found that complex 1 catalyzes the formation of benzyl benzoate from benzaldehyde in a Tishchenko reaction.

Entities:  

Year:  2018        PMID: 30124698     DOI: 10.1039/c8dt02933d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Synthesis, structural studies, and redox chemistry of bimetallic [Mn(CO)3] and [Re(CO)3] complexes.

Authors:  Wade C Henke; Tyler A Kerr; Thomas R Sheridan; Lawrence M Henling; Michael K Takase; Victor W Day; Harry B Gray; James D Blakemore
Journal:  Dalton Trans       Date:  2021-01-18       Impact factor: 4.390

  1 in total

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