Literature DB >> 30116822

Metal coordination induced ring contraction of porphyrin derivatives.

Bratati Patra1, Sebastian Sobottka, Sruti Mondal, Biprajit Sarkar, Sanjib Kar.   

Abstract

A remarkable rearrangement of a diferrocenylporphyrin to give a silver(iii) corrole has been discovered. Compared to the previously reported porphyrin to corrole ring conversions (extremely rare and poor reaction yields), our methodology delivers near quantitative yield for this ring contraction.

Entities:  

Year:  2018        PMID: 30116822     DOI: 10.1039/c8cc04670k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  UO2 2+-mediated ring contraction of pyrihexaphyrin: synthesis of a contracted expanded porphyrin-uranyl complex.

Authors:  James T Brewster; Harrison D Root; Daniel Mangel; Adam Samia; Hadiqa Zafar; Adam C Sedgwick; Vincent M Lynch; Jonathan L Sessler
Journal:  Chem Sci       Date:  2019-04-30       Impact factor: 9.825

  1 in total

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