Literature DB >> 30102045

Visible-Light-Induced C(sp2)-P Bond Formation by Denitrogenative Coupling of Benzotriazoles with Phosphites.

Yong Jian1, Ming Chen1, Binbin Huang1, Wei Jia1, Chao Yang1, Wujiong Xia1.   

Abstract

A visible-light-induced denitrogenative phosphorylation of benzotriazoles is presented, in which diverse substituted aryl phosphonates could be obtained in good to excellent yields. This efficient protocol exhibits good tolerance with various functional groups. Furthermore, the utility of this photochemical protocol is demonstrated by a gram-scale reaction, and a reasonable mechanism is proposed.

Entities:  

Year:  2018        PMID: 30102045     DOI: 10.1021/acs.orglett.8b02288

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  I2-mediated Csp2-P bond formation via tandem cyclization of o-alkynylphenyl isothiocyanates with organophosphorus esters.

Authors:  Yang Liu; Wenjin Wu; Xiaoyan Sang; Yu Xia; Guojian Fang; Wenyan Hao
Journal:  RSC Adv       Date:  2022-06-20       Impact factor: 4.036

2.  DIPEA-induced activation of OH- for the synthesis of amides via photocatalysis.

Authors:  Mei Wu; Sheng Huang; Huiqing Hou; Jie Lin; Mei Lin; Sunying Zhou; Zhiqiang Zheng; Weiming Sun; Fang Ke
Journal:  RSC Adv       Date:  2022-05-16       Impact factor: 4.036

3.  Benzotriazole as an Efficient Ligand in Cu-Catalyzed Glaser Reaction.

Authors:  Mala Singh; Anoop S Singh; Nidhi Mishra; Anand K Agrahari; Vinod K Tiwari
Journal:  ACS Omega       Date:  2019-01-31
  3 in total

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