Surface defect-mediated efficient electron-hole separation in hierarchical flower-like bismuth molybdate hollow spheres for enhanced visible-light-driven photocatalytic performance.

It is desirable to develop an efficient visible-light-driven photocatalyst for practical application to degrade highly-noxious pollutants. Herein, the hydrogenation hierarchical flower-like Bi2MoO6 hollow spheres (H-BMO-X, where X represents the different hydrogen calcination temperatures) have been successfully fabricated by a solvothermal-surface hydrogenation process. The as-prepared nano-photocatalyst H-BMO-300 clearly exhibits a photocatalytic reaction apparent rate constant k for high-noxious pollutants by ∼3-times higher than pristine Bi2MoO6. Moreover, the resultant H-BMO-300 sample with a narrow bandgap of ∼2.70 eV possesses surface oxygen vacancy defects. Based on the scanning Kelvin probe and surface photovoltage spectroscopy, it is deduced that the photocatalytic activities are attributed to the surface oxygen vacancy of H-BMO-X favoring the electron-hole pair's separation. The enhanced photocatalytic performance can be ascribed to the synergistic effect of surface defects favoring efficient electron-hole separation and the hollow hierarchical structure benefiting the utilization of visible light, which provides more surface-active sites. This work provides a viable route to perceptibly enhance the photocatalytic activities of H-BMO-300 for environmental remediation with good mineralization properties.