Black Phosphorus: Degradation Favors Lubrication.

Due to its innate instability, the degradation of black phosphorus (BP) with oxygen and moisture was considered the obstacle for its application in ambient conditions. Here, a friction force reduced by about 50% at the degraded area of the BP nanosheets was expressly observed using atomic force microscopy due to the produced phosphorus oxides during degradation. Energy-dispersive spectrometer mapping analyses corroborated the localized concentration of oxygen on the degraded BP flake surface where friction reduction was observed. Water absorption was discovered to be essential for the degraded characteristic as well as the friction reduction behavior of BP sheets. The combination of water molecules as well as the resulting chemical groups (P-OH bonds) that are formed on the oxidized surface may account for the friction reduction of degraded BP flakes. It is indicated that, besides its layered structure, the ambient degradation of BP significantly favors its lubrication behavior.