| Literature DB >> 30062851 |
Christoph Prichatz1, Monica Trincado2, Lilin Tan2,3, Fernando Casas2, Anja Kammer1, Henrik Junge1, Matthias Beller1, Hansjörg Grützmacher2,3.
Abstract
The ruthenium complex [RuH2 (PPh3 )4 ] is a competent catalyst for the selective dehydrogenation of formic acid (FA) at low temperature. It tolerates water and shows excellent performance (TOF up to 36 000 h-1 at 60 °C). Remarkably, no basic additives are necessary to obtain such high activity and the defined complex is stable for up to 120 days, making this system one of the most effective formic acid dehydrogenation catalysts known to date.Entities:
Keywords: dehydrogenation; formic acid; homogeneous catalysis; hydrogen; ruthenium
Year: 2018 PMID： 30062851 DOI： 10.1002/cssc.201801072
Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928