Literature DB >> 30059182

Photo-Electrochemical C-H Bond Activation of Cyclohexane Using a WO3 Photoanode and Visible Light.

Hiroyuki Tateno1, Shoji Iguchi1, Yugo Miseki1, Kazuhiro Sayama1.   

Abstract

The photo-electrochemical C-H bond activation of cyclohexane to produce cyclohexanol and cyclohexanone (KA oil) with high partial oxidation selectivity (99 %) and high current utilization ratio (76 %) was achieved in air at room temperature at atmospheric pressure. The production rate of KA oil was accelerated by applying a bias. The incident photon to current efficiencies at 365 and 420 nm were 57 % and 24 %, respectively.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H activation; alkanes; electrochemistry; oxidation; photocatalysis

Year:  2018        PMID： 30059182     DOI： 10.1002/anie.201805079

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  10 in total

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Review 2.  Beyond Water Oxidation: Hybrid, Molecular-Based Photoanodes for the Production of Value-Added Organics.

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Journal:  Front Chem       Date:  2022-05-25       Impact factor: 5.545

3.  Electrophotocatalytic Acetoxyhydroxylation of Aryl Olefins.

Authors:  He Huang; Tristan H Lambert
Journal:  J Am Chem Soc       Date:  2021-05-05       Impact factor: 15.419

4.  Electrophotocatalytic C-H Heterofunctionalization of Arenes.

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Journal:  Angew Chem Int Ed Engl       Date:  2021-04-12       Impact factor: 15.336

5.  Photoelectrocatalytic Arene C-H Amination.

Authors:  Lei Zhang; Laurent Liardet; Jingshan Luo; Dan Ren; Michael Grätzel; Xile Hu
Journal:  Nat Catal       Date:  2019-02-18

6.  Photoelectrocatalytic C-H halogenation over an oxygen vacancy-rich TiO2 photoanode.

Authors:  Zhenhua Li; Lan Luo; Min Li; Wangsong Chen; Yuguang Liu; Jiangrong Yang; Si-Min Xu; Hua Zhou; Lina Ma; Ming Xu; Xianggui Kong; Haohong Duan
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7.  Direct photoelectrochemical oxidation of hydroxymethylfurfural on tungsten trioxide photoanodes.

Authors:  Charles R Lhermitte; Nukorn Plainpan; Pamela Canjura; Florent Boudoire; Kevin Sivula
Journal:  RSC Adv       Date:  2020-12-23       Impact factor: 3.361

8.  Electrochemical [4 + 1] Tandem sp3(C-H) Double Amination for the Direct Synthesis of 3-Acyl-Functionalized Imidazo[1,5-a]pyridines.

Authors:  Qiang Wang; Xia Yao; Xian-Jing Xu; Shuai Zhang; Lei Ren
Journal:  ACS Omega       Date:  2022-01-27

9.  Photoelectrochemical alcohols oxidation over polymeric carbon nitride photoanodes with simultaneous H2 production.

Authors:  Neeta Karjule; Ravindra S Phatake; Shmuel Barzilai; Biswajit Mondal; Adi Azoulay; Alexander I Shames; Michael Volokh; Josep Albero; Hermenegildo García; Menny Shalom
Journal:  J Mater Chem A Mater       Date:  2022-07-25

10.  Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy.

Authors:  Stefano Crespi; Maurizio Fagnoni
Journal:  Chem Rev       Date:  2020-08-06       Impact factor: 60.622
  10 in total

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