| Literature DB >> 30039532 |
Maria F Espada1, Soukaina Bennaamane1, Qian Liao1, Nathalie Saffon-Merceron2, Stéphane Massou2, Eric Clot3, Noel Nebra1, Marie Fustier-Boutignon1, Nicolas Mézailles1.
Abstract
Intermolecular, stepwise functionalization by BH bonds of a (triphosphine)MoIV -nitrido complex generated by N2 splitting is reported. The imido-hydride and di-hydride-amido MoIV complexes have been isolated and characterized. Addition of PinBH to the [Mo(H)2 (N(BPin)2 )]+ complex at room temperature results in the liberation of borylamines from the metal center.Entities:
Keywords: N2 reduction; boranes; hydride ligands; molybdenum; nitride functionalization
Year: 2018 PMID： 30039532 DOI： 10.1002/anie.201805915
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336