Literature DB >> 30039127

Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds.

Tiebo Xiao1, Mingjing Mei, Yuwei He, Lei Zhou.   

Abstract

A blue light-promoted cross-coupling of two distinct diazo compounds was described. The reaction produces E-configured trisubstituted alkenes in good yields in the absence of catalysts and additives. The reactive free carbene intermediates were generated via selective photolysis of one of the two diazo compounds upon blue light irradiation.

Entities:  

Year:  2018        PMID： 30039127     DOI： 10.1039/c8cc04609c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  9 in total

1.  Photochemical ring expansion reactions: synthesis of tetrahydrofuran derivatives and mechanism studies.

Authors:  Sripati Jana; Zhen Yang; Chao Pei; Xinfang Xu; Rene M Koenigs
Journal:  Chem Sci       Date:  2019-09-06       Impact factor: 9.825

2.  Light-induced metal-free transformations of unactivated pyridotriazoles.

Authors:  Ziyan Zhang; Dongari Yadagiri; Vladimir Gevorgyan
Journal:  Chem Sci       Date:  2019-07-25       Impact factor: 9.825

3.  A combined experimental and theoretical study on the reactivity of nitrenes and nitrene radical anions.

Authors:  Yujing Guo; Chao Pei; Rene M Koenigs
Journal:  Nat Commun       Date:  2022-01-10       Impact factor: 14.919

4.  Blue Light-Promoted Cross-Coupling of α-Diazo Esters with Isocyanides: Synthesis of Ester-Functionalized Ketenimines.

Authors:  Pavel A Sakharov; Mikhail S Novikov; Tuan K Nguyen; Mikhail A Kinzhalov; Alexander F Khlebnikov; Nikolai V Rostovskii
Journal:  ACS Omega       Date:  2022-03-03

5.  Photocatalytic gem-Difluoroolefination Reactions by a Formal C-C Coupling/Defluorination Reaction with Diazoacetates.

Authors:  Fang Li; Chao Pei; Rene M Koenigs
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-09       Impact factor: 16.823

6.  Stoichiometric Photochemical Carbene Transfer by Bamford-Stevens Reaction.

Authors:  Sripati Jana; Fang Li; Claire Empel; Dennis Verspeek; Polina Aseeva; Rene M Koenigs
Journal:  Chemistry       Date:  2020-02-21       Impact factor: 5.236

7.  Visible Light Induced Metal-Free Carbene N-Carbazolation.

Authors:  Claire Empel; Frederic W Patureau; Rene M Koenigs
Journal:  J Org Chem       Date:  2019-08-15       Impact factor: 4.354

Review 8.  Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions.

Authors:  Sripati Jana; Yujing Guo; Rene M Koenigs
Journal:  Chemistry       Date:  2020-10-29       Impact factor: 5.236

9.  Proton or Carbene Transfer? On the Dark and Light Reaction of Diazoalkanes with Alcohols.

Authors:  Claire Empel; Chao Pei; Feifei He; Sripati Jana; Rene M Koenigs
Journal:  Chemistry       Date:  2022-02-17       Impact factor: 5.020
  9 in total

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