Literature DB >> 30035862

Three-Dimensional Heterocycles by Iron-Catalyzed Ring-Closing Sulfoxide Imidation.

Hao Yu1, Zhen Li1, Carsten Bolm1.   

Abstract

A general and atom-economical method for the synthesis of cyclic sulfoximines by intramolecular imidations of azido-containing sulfoxides using a commercially available FeII phthalocyanine (FeII Pc) as catalyst has been developed. The method conveys a broad functional group tolerance and the resulting three-dimensional heterocycles can be modified by cross-coupling reactions.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  azides; cyclic sulfoximines; intramolecular imidation; iron; nitrene transfer

Year:  2018        PMID： 30035862     DOI： 10.1002/anie.201804284

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Decarbonylative Sulfide Synthesis from Carboxylic Acids and Thioesters via Cross-Over C-S Activation and Acyl Capture.

Authors:  Chengwei Liu; Michal Szostak
Journal:  Org Chem Front       Date:  2021-06-22       Impact factor: 5.456

2.  Modular Sulfondiimine Synthesis Using a Stable Sulfinylamine Reagent.

Authors:  Ze-Xin Zhang; Thomas Q Davies; Michael C Willis
Journal:  J Am Chem Soc       Date:  2019-08-09       Impact factor: 15.419

3.  Organocatalytic atroposelective construction of axially chiral N, N- and N, S-1,2-azoles through novel ring formation approach.

Authors:  Yu Chang; Chuandong Xie; Hong Liu; Shengli Huang; Pengfei Wang; Wenling Qin; Hailong Yan
Journal:  Nat Commun       Date:  2022-04-11       Impact factor: 14.919

Review 4.  (Hetero)aryl-SVI Fluorides: Synthetic Development and Opportunities.

Authors:  Marc Magre; Shengyang Ni; Josep Cornella
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-27       Impact factor: 16.823

Review 5.  Azides and Porphyrinoids: Synthetic Approaches and Applications. Part 1-Azides, Porphyrins and Corroles.

Authors:  Ana R L Araújo; Augusto C Tomé; Carla I M Santos; Maria A F Faustino; Maria G P M S Neves; Mário M Q Simões; Nuno M M Moura; Sultan T Abu-Orabi; José A S Cavaleiro
Journal:  Molecules       Date:  2020-04-03       Impact factor: 4.411
  5 in total

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