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Literature DB >> 30035861

Photoredox Catalysis as a Strategy for CO₂ Incorporation: Direct Access to Carboxylic Acids from a Renewable Feedstock.

Abstract

Carbon dioxide is an attractive reagent for organic synthesis from the standpoint of global sustainability. Its widespread use, however, is hampered by the fact that it is poorly reactive. New catalysts and technologies that enable C-C bond constructions are thus of high intrinsic value. This Minireview describes recent advances in the area of photoredox catalysis as an enabling strategy for promoting carboxylations.

Entities: Chemical

Keywords: carbon dioxide fixation; carboxylation; carboxylic acids; photocatalysis; radical reactions

Year: 2019 PMID： 30035861 DOI： 10.1002/anie.201806285

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

11 in total

Review 1. Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.

Authors: Laura Buglioni; Fabian Raymenants; Aidan Slattery; Stefan D A Zondag; Timothy Noël
Journal: Chem Rev Date: 2021-08-10 Impact factor: 60.622

Photoredox Catalysis as a Strategy for CO₂ Incorporation: Direct Access to Carboxylic Acids from a Renewable Feedstock.

Review 1. Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.

2. Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO₂.

3. Ni(I)-Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO₂ Insertion at Ni(I) Centers.

4. Visible light-promoted CO₂ fixation with imines to synthesize diaryl α-amino acids.

5. Photocarboxylation of Benzylic C-H Bonds.

6. Site-Selective, Remote sp³ C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis.

7. Ligand and solvent effects on CO₂ insertion into group 10 metal alkyl bonds.

8. Metal Ion Promiscuity and Structure of 2,3-Dihydroxybenzoic Acid Decarboxylase of Aspergillus oryzae.

9. Photocatalytic synthesis of tetra-substituted furans promoted by carbon dioxide.

10. Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO₂.