| Literature DB >> 30029352 |
Simone Braeuer1, Jan Borovička2, Toma Glasnov1, Gema Guedes de la Cruz1, Kenneth B Jensen1, Walter Goessler3.
Abstract
The arsenic speciation was determined in macrofungi of the Ramaria genus with HPLC coupled to inductively coupled plasma mass spectrometry. Besides arsenic species that are already known for macrofungi, like arsenobetaine or arsenocholine, two compounds that were only known from marine samples so far (trimethylarsoniopropanate and dimethylarsinoylacetate) were found for the first time in a terrestrial sample. An unknown arsenical was isolated and identified as homoarsenocholine. This could be a key intermediate for further elucidation of the biotransformation mechanisms of arsenic.Entities:
Keywords: (3-hydroxypropyl) trimethylarsonium ion; Arsenic speciation; Fungi; Homoarsenocholine; ICPMS; Ramaria
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Year: 2018 PMID: 30029352 PMCID: PMC6118324 DOI: 10.1016/j.talanta.2018.05.065
Source DB: PubMed Journal: Talanta ISSN: 0039-9140 Impact factor: 6.057