Literature DB >> 30024748

Branch-Selective and Enantioselective Iridium-Catalyzed Alkene Hydroarylation via Anilide-Directed C-H Oxidative Addition.

Simon Grélaud1, Phillippa Cooper1, Lyman J Feron2, John F Bower1.   

Abstract

Tertiary benzylic stereocenters are accessed in high enantioselectivity by Ir-catalyzed branch selective addition of anilide ortho-C-H bonds across styrenes and α-olefins. Mechanistic studies indicate that the stereocenter generating step is reversible.

Entities:  

Year:  2018        PMID： 30024748     DOI： 10.1021/jacs.8b04627

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Regio- and Diastereoselective Iron-Catalyzed [4+4]-Cycloaddition of 1,3-Dienes.

Authors:  C Rose Kennedy; Hongyu Zhong; Rachel L Macaulay; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2019-05-16       Impact factor: 15.419

2.  Branched-Selective Direct α-Alkylation of Cyclic Ketones with Simple Alkenes.

Authors:  Dong Xing; Xiaotian Qi; Daniel Marchant; Peng Liu; Guangbin Dong
Journal:  Angew Chem Int Ed Engl       Date:  2019-02-21       Impact factor: 15.336

3.  A Transient-Directing-Group Strategy Enables Enantioselective Reductive Heck Hydroarylation of Alkenes.

Authors:  Lucas J Oxtoby; Zi-Qi Li; Van T Tran; Tuğçe G Erbay; Ruohan Deng; Peng Liu; Keary M Engle
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-07       Impact factor: 15.336

4.  Catalytic α-Hydroarylation of Acrylates and Acrylamides via an Interrupted Hydrodehalogenation Reaction.

Authors:  Alena M Vasquez; John A Gurak; Candice L Joe; Emily C Cherney; Keary M Engle
Journal:  J Am Chem Soc       Date:  2020-05-28       Impact factor: 15.419

5.  Iridium-Catalyzed α-Selective Arylation of Styrenes by Dual C-H Functionalization.

Authors:  Phillippa Cooper; Giacomo E M Crisenza; Lyman J Feron; John F Bower
Journal:  Angew Chem Int Ed Engl       Date:  2018-09-26       Impact factor: 15.336

6.  Strong and Confined Acids Catalyze Asymmetric Intramolecular Hydroarylations of Unactivated Olefins with Indoles.

Authors:  Pinglu Zhang; Nobuya Tsuji; Jie Ouyang; Benjamin List
Journal:  J Am Chem Soc       Date:  2021-01-05       Impact factor: 15.419

7.  Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C-H activation.

Authors:  Dingyi Wang; Ben Dong; Yandong Wang; Jiasheng Qian; Jinjun Zhu; Yue Zhao; Zhuangzhi Shi
Journal:  Nat Commun       Date:  2019-08-06       Impact factor: 14.919

8.  Iridium(I)-Catalyzed Isoindolinone-Directed Branched-Selective Aromatic C-H Alkylation with Simple Alkenes.

Authors:  Maoqian Xiong; Yuhang Shu; Jie Tang; Fan Yang; Dong Xing
Journal:  Molecules       Date:  2022-03-16       Impact factor: 4.411
  8 in total

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