Literature DB >> 30009305

[RuII(tpy)(bpy)Cl]+-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects.

T W Schneider1, M T Hren, M Z Ertem, A M Angeles-Boza.   

Abstract

In this work, we examine the use of competitive 13C kinetic isotope effects (13C KIEs) on CO2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13C KIE measurements and theoretical calculations methodology for probing CO2 conversion reactions.

Entities:  

Year:  2018        PMID: 30009305     DOI: 10.1039/c8cc03009j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Dual electronic effects achieving a high-performance Ni(II) pincer catalyst for CO2 photoreduction in a noble-metal-free system.

Authors:  Hai-Hua Huang; Ji-Hong Zhang; Miao Dai; Lianglin Liu; Zongren Ye; Jiahao Liu; Di-Chang Zhong; Jia-Wei Wang; Cunyuan Zhao; Zhuofeng Ke
Journal:  Proc Natl Acad Sci U S A       Date:  2022-08-23       Impact factor: 12.779

2.  Mechanistic insights into CO2 conversion chemistry of copper bis-(terpyridine) molecular electrocatalyst using accessible operando spectrochemistry.

Authors:  Huihui Zhang; Chang Xu; Xiaowen Zhan; Yu Yu; Kaifu Zhang; Qiquan Luo; Shan Gao; Jinlong Yang; Yi Xie
Journal:  Nat Commun       Date:  2022-10-13       Impact factor: 17.694

  2 in total

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