Literature DB >> 29993055

Mechanochemical dehydrocoupling of dimethylamine borane and hydrogenation reactions using Wilkinson's catalyst.

Christian Schumacher1, Deborah E Crawford, Branimir RaguŽ, Robert Glaum, Stuart L James, Carsten Bolm, José G Hernández.   

Abstract

Mechanochemistry enabled the selective synthesis of the recherché orange polymorph of Wilkinson's catalyst [RhCl(PPh3)3]. The mechanochemically prepared Rh-complex catalysed the solvent-free dehydrogenation of Me2NH·BH3 in a ball mill. The in situ-generated hydrogen (H2) could be utilised for Rh-catalysed hydrogenation reactions by ball milling.

Entities:  

Year:  2018        PMID： 29993055     DOI： 10.1039/c8cc04487b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Mechanochemistry: New Tools to Navigate the Uncharted Territory of "Impossible" Reactions.

Authors:  Federico Cuccu; Lidia De Luca; Francesco Delogu; Evelina Colacino; Niclas Solin; Rita Mocci; Andrea Porcheddu
Journal:  ChemSusChem       Date:  2022-07-21       Impact factor: 9.140

2.  Mechanochemical Palladium-Catalyzed Carbonylative Reactions Using Mo(CO)6.

Authors:  Pit van Bonn; Carsten Bolm; José G Hernández
Journal:  Chemistry       Date:  2020-02-11       Impact factor: 5.236

Review 3.  Direct Mechanocatalysis: Using Milling Balls as Catalysts.

Authors:  Wilm Pickhardt; Sven Grätz; Lars Borchardt
Journal:  Chemistry       Date:  2020-09-03       Impact factor: 5.236

4.  Mechanochemical P-derivatization of 1,3,5-Triaza-7-Phosphaadamantane (PTA) and Silver-Based Coordination Polymers Obtained from the Resulting Phosphabetaines.

Authors:  Antal Udvardy; Csenge Tamara Szolnoki; Réka Gombos; Gábor Papp; Éva Kováts; Ferenc Joó; Ágnes Kathó
Journal:  Molecules       Date:  2020-11-16       Impact factor: 4.411

5.  Mechanochemical Grignard Reactions with Gaseous CO2 and Sodium Methyl Carbonate.

Authors:  Victoria S Pfennig; Romina C Villella; Julia Nikodemus; Carsten Bolm
Journal:  Angew Chem Int Ed Engl       Date:  2022-01-19       Impact factor: 16.823
  5 in total

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