Literature DB >> 29975060

Pd-Catalyzed Dearomative Allylation of Benzyl Phosphates.

Masaaki Komatsuda1, Kei Muto1, Junichiro Yamaguchi1.   

Abstract

Dearomative C-C bond formation of benzyl phosphates has been developed. In the presence of a palladium/PAr3 catalyst, benzyl phosphates reacted with allyl borates to generate the allylated product in a dearomative fashion. The resulting dearomatized molecules were successfully derivatized by Simmons-Smith cyclopropanation and oxidation.

Entities:  

Year:  2018        PMID： 29975060     DOI： 10.1021/acs.orglett.8b01807

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Palladium-Catalyzed Dearomative syn-1,4-Carboamination with Grignard Reagents.

Authors:  Conghui Tang; Mikiko Okumura; Yunbo Zhu; Annie R Hooper; Yu Zhou; Yu-Hsuan Lee; David Sarlah
Journal:  Angew Chem Int Ed Engl       Date:  2019-06-24       Impact factor: 15.336

2.  Palladium-catalyzed dearomative 1,4-difunctionalization of naphthalenes.

Authors:  Ping Yang; Chao Zheng; Yu-Han Nie; Shu-Li You
Journal:  Chem Sci       Date:  2020-06-10       Impact factor: 9.825

3.  A regioselectivity switch in Pd-catalyzed hydroallylation of alkynes.

Authors:  Ding-Wei Ji; Yan-Cheng Hu; Hao Zheng; Chao-Yang Zhao; Qing-An Chen; Vy M Dong
Journal:  Chem Sci       Date:  2019-05-16       Impact factor: 9.825

4.  Palladium-catalysed difluoroolefination of benzyl tosylates toward the synthesis of gem-difluoro-2-trifluromethyl styrene derivatives.

Authors:  Jie Xu; Jiangjun Liu; Gang Chen; Baojian Xiong; Xuemei Zhang; Zhong Lian
Journal:  RSC Adv       Date:  2022-04-28       Impact factor: 4.036

5.  Electrophilic Trapping of Semibenzenes.

Authors:  Cosimo Boldrini; Marta Castiñeira Reis; Syuzanna R Harutyunyan
Journal:  J Org Chem       Date:  2022-09-12       Impact factor: 4.198

6.  Pd-catalyzed allylative dearomatisation using Grignard reagents.

Authors:  Cosimo Boldrini; Syuzanna R Harutyunyan
Journal:  Chem Commun (Camb)       Date:  2021-11-09       Impact factor: 6.222
  6 in total

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