Literature DB >> 29959826

Construction of Quaternary Stereocenters by Palladium-Catalyzed Carbopalladation-Initiated Cascade Reactions.

Yuanyuan Ping1, Yuxiu Li1, Jieping Zhu2, Wangqing Kong1.   

Abstract

The enantioselective synthesis of molecules containing quaternary stereocenters is a field of intense research interest and development. Among the known organic transformations, carbopalladation-initiated domino transformations constitutes a general method for the construction of compounds containing cyclic or spiro quaternary stereocenters. In this Minireview, recent achievements in palladium-catalyzed domino Heck/C-H functionalizations and developments in enantioselective carbopalladation-initiated domino processes are summarized.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  C−H functionalization; asymmetric synthesis; domino process; homogeneous catalysis; quaternary stereocenters

Year:  2018        PMID： 29959826     DOI： 10.1002/anie.201806088

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  11 in total

1.  Development and Elucidation of a Pd-Based Cyclization-Oxygenation Sequence for Natural Product Synthesis.

Authors:  Heng Yi; Pengfei Hu; Scott A Snyder
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-08       Impact factor: 15.336

2.  Palladium-catalyzed dearomative 1,4-difunctionalization of naphthalenes.

Authors:  Ping Yang; Chao Zheng; Yu-Han Nie; Shu-Li You
Journal:  Chem Sci       Date:  2020-06-10       Impact factor: 9.825

3.  An Approach toward 17-Arylsubstituted Marginatafuran-Type Isospongian Diterpenoids via a Palladium-Catalyzed Heck-Suzuki Cascade Reaction of 16-Bromolambertianic Acid.

Authors:  Yurii V Kharitonov; Elvira E Shults
Journal:  Molecules       Date:  2022-04-20       Impact factor: 4.927

4.  Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids.

Authors:  Yun Zhang; Gong Chen; Dongbing Zhao
Journal:  Chem Sci       Date:  2019-07-03       Impact factor: 9.825

5.  Construction of sterically congested oxindole derivatives via visible-light-induced radical-coupling.

Authors:  Yanling Shen; Ning Lei; Cong Lu; Dailin Xi; Xinxin Geng; Pan Tao; Zhishan Su; Ke Zheng
Journal:  Chem Sci       Date:  2021-11-17       Impact factor: 9.825

6.  Synthesis of dihydroisoquinolinone-4-methylboronic esters via domino Heck/borylation using a structurally characterized palladacycle as a catalyst.

Authors:  Jhansi Rani Morla; Dastagiri Reddy Nareddula
Journal:  RSC Adv       Date:  2022-02-28       Impact factor: 3.361

Review 7.  Catalytic enantioselective construction of vicinal quaternary carbon stereocenters.

Authors:  Feng Zhou; Lei Zhu; Bo-Wen Pan; Yang Shi; Yun-Lin Liu; Jian Zhou
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825

8.  Nickel-catalyzed three-component olefin reductive dicarbofunctionalization to access alkylborates.

Authors:  Xiao-Xu Wang; Xi Lu; Shi-Jiang He; Yao Fu
Journal:  Chem Sci       Date:  2020-07-08       Impact factor: 9.825

9.  Enantioselective palladium/copper-catalyzed C-C σ-bond activation synergized with Sonogashira-type C(sp3)-C(sp) cross-coupling alkynylation.

Authors:  Feng-Na Sun; Wan-Chun Yang; Xiao-Bing Chen; Yu-Li Sun; Jian Cao; Zheng Xu; Li-Wen Xu
Journal:  Chem Sci       Date:  2019-06-21       Impact factor: 9.825

10.  Synthesis of Spiroindenyl-2-Oxindoles through Palladium-Catalyzed Spirocyclization of 2-Bromoarylamides and Vinyl Bromides.

Authors:  Shuai Yang; Yanghui Zhang
Journal:  Molecules       Date:  2021-12-10       Impact factor: 4.411
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