Hierarchical Cobalt-Based Metal-Organic Framework for High-Performance Lithium-Ion Batteries.

In the present work, a simple solvothermal method is developed for the synthesis of hierarchical Co-based metal-organic framework (H-Co-MOF) microflowers. These microflowers are composed of nanosheets, consisting of small nanoflakes. Upon application as an electrode material in Li-ion batteries, H-Co-MOF shows ultrahigh specific capacity and long cycling performance. For instance, a remarkably superior capacity of 1345 mA h g-1 can be achieved after 100 cycles at a current density of 0.1 A g-1 . Even at 2 A g-1 , a large capacity of 828 mA h g-1 is maintained after 700 cycles. This excellent electrochemical performance might be ascribed to the intrinsic properties and unique hierarchical structure of the Co-based MOF.