Ternary CuZnS Nanocrystals: Synthesis, Characterization, and Interfacial Application in Perovskite Solar Cells.

Ternary CuZnS nanocrystals (NCs) are synthesized via a facile, scalable, noninjection method at low temperatures for the first time, wherein sodium ascorbate plays the dual roles of reducing agent and capping ligand in the preparation process. These NCs can be dispersed well in a polar solvent like dimethyl sulfoxide, and the average size is ∼4 nm as measured by transmission electron microscopy. The results of X-ray diffraction and X-ray photoelectron spectroscopy indicate that the crystal structure of CuZnS NCs displays covellite CuS-like structure and the Zn element partly occupies the Cu position. Also, the crystal structure of CuZnS NCs is completely converted from a covellite CuS structure into a digenite Cu9S5 structure when the NCs are treated above 350 °C. Moreover, CuZnS NCs demonstrate favorable hole transport properties. When it is employed in MAPbI3-based perovskite solar cells as a hole transport layer, a peak power conversion efficiency of 18.3% is achieved. Simultaneously, the devices based on CuZnS exhibit a remarkably reduced J-V hysteresis. The results indicate that CuZnS is a promising hole transport layer for enhancing perovskite solar cell performance and presents great potential for optoelectronic applications, as well.