Aggregation Behavior of Multiwalled Carbon Nanotube-Titanium Dioxide Nanohybrids: Probing the Part-Whole Question.

Multiwalled carbon nanotube-titanium dioxide (MWNT-TiO2) nanohybrids (NHs), a promising support for electrocatalysts, have a high likelihood of environmental release. Aggregation of these NHs may or may not be captured by the sum of their component behavior, thus necessitating a systematic evaluation. This study probes the "part-whole question" by systematically evaluating the role of TiO2 loading (C:Ti molar ratios of 1:0.1, 1:0.05 and 1:0.033) on the aggregation behavior of these NHs. Aggregation kinetics of these in-house synthesized (using a sol-gel method) NHs and the components is investigated with time-resolved dynamic light scattering in the presence of mono- and divalent cations and with and without Suwannee River humic acid. A deviation in the aggregation behavior from classical electrokinetic theory has been observed which indicates that the material complexity has a strong influence in the observed behavior; hence other material attributes (e.g., fractal dimension, surface roughness, charge heterogeneity, etc.) should be carefully considered when studying such materials. The sum of the aggregation behavior of the parts may not capture that of the whole (i.e., of the NHs); aggregation depends on the TiO2 loading and also on the hybridization process and the background aquatic chemistry.