Literature DB >> 29939465

Realizing the Potential of Acetylenedicarboxylate by Functionalization to Halofumarate in ZrIV Metal-Organic Frameworks.

Tobie J Matemb Ma Ntep1, Helge Reinsch2, Bastian Moll1, Emrah Hastürk1, Serkan Gökpinar1, Hergen Breitzke3, Carsten Schlüsener1, Laura Schmolke1, Gerd Buntkowsky3, Christoph Janiak1.   

Abstract

A strategy was developed to obtain from acetylenedicarboxylic acid either an acetylenedicarboxylate-based ZrIV metal-organic framework (MOF) with fcu topology or a halo-functionalized-MOF-801 through in situ ligand hydrohalogenation. The new materials feature exceptionally high hydrophilicity and CO2 /H2 adsorption energetics. The acetylenedicarboxylate linker and its functionalizable triple-bond discloses its potential in the engineering of microporous materials with targeted properties.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  acetylenedicarboxylate; gas adsorption; hydrophilicity; in situ functionalization; metal-organic frameworks

Year:  2018        PMID： 29939465     DOI： 10.1002/chem.201802838

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  1 in total

1.  Eu(O2 C-C≡C-CO2 ): An EuII Containing Anhydrous Coordination Polymer with High Stability and Negative Thermal Expansion.

Authors:  Verena K Gramm; Daniel Smets; Ireneus Grzesiak; Theresa Block; Rainer Pöttgen; Markus Suta; Claudia Wickleder; Thomas Lorenz; Uwe Ruschewitz
Journal:  Chemistry       Date:  2020-02-11       Impact factor: 5.236
  1 in total

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