Optical microscopy as a new approach for characterising dust particulates in urban environment.

In urban environments airborne particulates (dust) must be managed to ensure that industry and community coexist in a mutually beneficial and sustainable manner. The composition of the dust is a function of the local environment and industry. In general, there is a view by many community members that a significant proportion of inhalable (PM10) and respirable (PM2.5) dust in these environments could be coal. Thus there is a need to have an analytical method that provides a quantitative analysis of the amount and size distribution of the different particulates that can be present in air samples. Australia's national research body, the Commonwealth Scientific and Industrial Research Organisation (CSIRO) has developed a Coal Grain Analysis (CGA) system that uses reflected light optical microscopy to provide a unique visual perspective, a qualitative feeling of the sample and quantitative information on the composition and size of the individual particles greater than 1 μm. Furthermore, semi-automated Optical Dust Marker software uses each individual particle's colour reflectance fingerprint to classify that particle. These markers can currently identify coal, combustion chars, iron, quartz/dark minerals, pyrite/bright materials and particulates of organic origin. This paper presents a case study performed using CGA to evaluate the dust composition and proportion of coal and other particulates and also their size distribution in samples collected in an urban area along a coal rail corridor in Newcastle (Australia). In coastal environments a significant proportion of dust can be water soluble (salt) particulates; the proportion of soluble particulates in those samples varied from 46% to 52.3%. The concentration of insoluble particles in samples varied from 5.9 to 15.5 μg m-3 in the PM2.5-10 fraction and from 0.4 to 0.9 μg m-3 in the PM1-2.5 fraction. All samples consisted predominantly of particles of organic origin (mostly plant and insect remains) - 55.3%-85.3% by mass. Dark material particles of mainly inorganic origin (low reflecting material, mainly stone dust, clay, soot, rubber and soil), combustion char and metal particles (rust and iron oxides) were present in lower concentrations - 0.0% to 19.9% by mass. The amount of coal in the water insoluble fraction of the samples ranged from 5.3% to 19.7% by mass with 2.9%-13.5% by mass of coal particles in the thoracic (2.5-10 μm) and 0.3%-1.2% by mass in the respirable (1-2.5 μm) size fraction. Crown