| Literature DB >> 29927588 |
James T Brewster1, Hadiqa Zafar1, Matthew McVeigh1, Christopher D Wight1, Gonzalo Anguera1, Axel Steinbrück1, Vincent M Lynch1, Jonathan L Sessler1,2.
Abstract
The controlled preparation of higher order oligopyrrolic species holds broad utility across the chemical and material sciences. Here, we describe the gram-scale synthesis of a bench-stable 5,5″-unsubstituted terpyrrole in excellent yield via a tandem Suzuki cross-coupling with in situ deprotection. The solution and solid-state stability as well as UV-vis, fluorescence, and single crystal X-ray diffraction structure are also detailed.Entities:
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Year: 2018 PMID： 29927588 PMCID： PMC6381930 DOI： 10.1021/acs.joc.8b01333
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354