| Literature DB >> 29902656 |
Aswin Sriram1, Ganapathiraman Swaminathan2.
Abstract
In the present study, thermogravimetric analysis of Musa balbisiana flower petal was carried out to study the degradation behaviour and the kinetics in the pyrolytic reaction. The pyrolysis was carried out in the temperature range of 35-900 °C at different heating rates of 5, 10 and 20 °C/min. The kinetics was investigated using different models like Kissinger-Akahira-Sunose (KAS), Flynn-Ozawa-Wall (FOW), Friedman and Broido's plot. The average Ea values determined by KAS, FOW and Friedman methods were 137.94, 136.76 and 133.36 kJ/mol respectively. Coats-Redfern method was utilized to determine the pre-exponential factors and the reaction order of the pyrolysis. For the conversion rates 0.1 and 0.2, both Valensi and Ginstling diffusion models were found out to be appropriate for the solid state reaction mechanism. The HHV of Musa balbisiana flower petal was 16.35 MJ/kg, suggested as a potential bio-feedstock energy source from agro-waste.Entities:
Keywords: Activation energy; Musa balbisiana; Pyrolysis; Reaction kinetics; Thermogravimetric studies
Mesh:
Year: 2018 PMID: 29902656 DOI: 10.1016/j.biortech.2018.05.043
Source DB: PubMed Journal: Bioresour Technol ISSN: 0960-8524 Impact factor: 9.642