Literature DB >> 29900463

Visible light mediated desilylative C(sp2)-C(sp2) cross-coupling reactions of arylsilanes with aryldiazonium salts under Au(i)/Au(iii) catalysis.

Indradweep Chakrabarty1, Manjur O Akram, Suprakash Biswas, Nitin T Patil.   

Abstract

Desilylative C(sp2)-C(sp2) cross-coupling reactions of arylsilanes with aryldiazonium salts under Au(i)/photoredox catalysis have been reported. The addition of Cu-salts as catalysts was found to be crucial for the success of this transformation.

Entities:  

Year:  2018        PMID： 29900463     DOI： 10.1039/c8cc03925a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Light-Induced Mechanistic Divergence in Gold(I) Catalysis: Revisiting the Reactivity of Diazonium Salts.

Authors:  Svenja Taschinski; René Döpp; Martin Ackermann; Frank Rominger; Folkert de Vries; Maximilian F S J Menger; Matthias Rudolph; A Stephen K Hashmi; Johannes E M N Klein
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-11       Impact factor: 15.336

2.  Modular and Selective Arylation of Aryl Germanes (C-GeEt3 ) over C-Bpin, C-SiR3 and Halogens Enabled by Light-Activated Gold Catalysis.

Authors:  Grant J Sherborne; Avetik G Gevondian; Ignacio Funes-Ardoiz; Amit Dahiya; Christoph Fricke; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-12       Impact factor: 15.336
  2 in total

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