| Literature DB >> 29878012 |
Alexander F R Kilpatrick1, Fu-Sheng Guo2, Benjamin M Day2, Akseli Mansikkamäki3, Richard A Layfield1, F Geoffrey N Cloke1.
Abstract
The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2- ligand.Entities:
Year: 2018 PMID： 29878012 DOI： 10.1039/c8cc03516d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222