Investigation of the long-term desalination performance of membrane capacitive deionization at the presence of organic foulants.

A long-term performance of membrane capacitive deionization (MCDI) was investigated at the presence of organic matter, which has contributed to the understanding of fouling phenomena and energy efficiency. The commercial humic acid and sodium alginate were adopted as model substances representative of natural organic matter, and different ions including sodium and calcium were selected as important parameters considered in both model substances. The experimental results showed reductions in the salinity removal ability and increments of energy usage due to the organic fouling of ion-exchange membranes and carbon electrodes. Within a time interval of approximately 15 d, reductions of NaCl adsorbance with 5.3 and 3.3 mg per cycle were obtained for humics and alginate, respectively. Simultaneously, the energy consumptions increased by 56.9% for humics and 26.3% for alginate. Furthermore, the results in terms of calcium removal in organic feed and energy usage showed that it had a higher fouling potential in comparison to the ones for the sodium solution with equal conductivity and organic concentration. The morphology and composition of the fouling layer were further studied, and it was found that the organic adsorption onto the electrodes and the attachment or even penetration of organic matter on or into the ion-exchange membrane, which could not be efficiently desorbed during the regeneration cycle, were determined as a key problem of demineralized water production. Therefore, this study suggested the necessity of a pre-treatment to reduce the presence of organic matter for the sustainable operation of MCDI, hereby broaden the potential application fields.