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Literature DB >> 29873233

Adducts of Triallylborane with Ammonia and Aliphatic Amines as Stoichiometric Allylating Agents for Aminoallylation Reaction of Carbonyl Compounds.

Nikolai Yu Kuznetsov¹, Rabdan M Tikhov¹, Tatiana V Strelkova¹, Yuri N Bubnov¹.

Abstract

Triallylborane-amines adducts are effective stoichiometric allylating agents in the aminoallylation reaction of carbonyl compounds in methanol. Moreover, copper-catalyzed diastereoselective allylation of Ellman's imine was achieved with triallylborane-methylamine adduct.

Entities: Chemical

Year: 2018 PMID： 29873233 DOI： 10.1021/acs.orglett.8b01317

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

1 in total

1. Deoxygenative α-alkylation and α-arylation of 1,2-dicarbonyls.

Authors: Shengfei Jin; Hang T Dang; Graham C Haug; Viet D Nguyen; Hadi D Arman; Oleg V Larionov
Journal: Chem Sci Date: 2020-07-01 Impact factor: 9.825

1 in total