Literature DB >> 29869658

Four-electron reduction chemistry using a uranium(iii) phosphido complex.

Pokpong Rungthanaphatsophon1, Charles L Barnes, Steven P Kelley, Justin R Walensky.   

Abstract

The first uranium(iii) phosphido complex is reported. The reaction of (C5Me5)2UI(THF) with KP[(C6H2Me3-2,4,6)(SiMe3)] affords (C5Me5)2U[P(C6H2Me3-2,4,6)(SiMe3)](THF), 1. The reactivity of 1 was explored with two equivalents of N3SiMe3 and N3Ad, Ad = adamantyl, both of which produce U(vi) bis(imido) complexes via four-electron reduction of the azides.

Entities:  

Year:  2018        PMID： 29869658     DOI： 10.1039/c8dt01406j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Nitrogen activation and cleavage by a multimetallic uranium complex.

Authors:  Megan Keener; Farzaneh Fadaei-Tirani; Rosario Scopelliti; Ivica Zivkovic; Marinella Mazzanti
Journal:  Chem Sci       Date:  2022-06-22       Impact factor: 9.969

2.  Uranium versus Thorium: Synthesis and Reactivity of [η5 -1,2,4-(Me3 C)3 C5 H2 ]2 U[η2 -C2 Ph2 ].

Authors:  Deqiang Wang; Wanjian Ding; Guohua Hou; Guofu Zi; Marc D Walter
Journal:  Chemistry       Date:  2021-03-16       Impact factor: 5.236

3.  Single metal four-electron reduction by U(ii) and masked "U(ii)" compounds.

Authors:  Dieuwertje K Modder; Chad T Palumbo; Iskander Douair; Rosario Scopelliti; Laurent Maron; Marinella Mazzanti
Journal:  Chem Sci       Date:  2021-03-22       Impact factor: 9.825

4.  Divergent uranium- versus phosphorus-based reduction of Me3SiN3 with steric modification of phosphido ligands.

Authors:  Robert J Ward; Pokpong Rungthanaphatsophon; Iker Del Rosal; Steven P Kelley; Laurent Maron; Justin R Walensky
Journal:  Chem Sci       Date:  2020-05-27       Impact factor: 9.825
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.