Literature DB >> 29862397

Ambiphilic geometrically constrained phosphenium cation.

Solomon Volodarsky1, Roman Dobrovetsky.   

Abstract

In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.

Entities:  

Year:  2018        PMID: 29862397     DOI: 10.1039/c8cc02423e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  8 in total

1.  Geometrically constrained square pyramidal phosphoranide.

Authors:  Solomon Volodarsky; Irina Malahov; Deependra Bawari; Mohand Diab; Naveen Malik; Boris Tumanskii; Roman Dobrovetsky
Journal:  Chem Sci       Date:  2022-04-27       Impact factor: 9.969

2.  Enthalpy-Controlled Insertion of a "Nonspectator" Tricoordinate Phosphorus Ligand into Group 10 Transition Metal-Carbon Bonds.

Authors:  Seung Jun Hwang; Akira Tanushi; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2020-12-11       Impact factor: 15.419

3.  Transient Phosphenium and Arsenium Ions versus Stable Stibenium and Bismuthenium Ions.

Authors:  Marian Olaru; Daniel Duvinage; Enno Lork; Stefan Mebs; Jens Beckmann
Journal:  Chemistry       Date:  2019-10-24       Impact factor: 5.236

4.  Calix[4]pyrrolato Aluminates: The Effect of Ligand Modification on the Reactivity of Square-Planar Aluminum Anions.

Authors:  Fabian Ebner; Philipp Mainik; Lutz Greb
Journal:  Chemistry       Date:  2021-02-24       Impact factor: 5.236

5.  Metal-Free N-H Bond Activation by Phospha-Wittig Reagents.

Authors:  Fabian Dankert; Jan-Erik Siewert; Priyanka Gupta; Florian Weigend; Christian Hering-Junghans
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-04       Impact factor: 16.823

6.  Dual Reactivity of a Geometrically Constrained Phosphenium Cation.

Authors:  Solomon Volodarsky; Deependra Bawari; Roman Dobrovetsky
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-27       Impact factor: 16.823

7.  Reversible OH-bond activation and amphoterism by metal-ligand cooperativity of calix[4]pyrrolato aluminate.

Authors:  Lukas M Sigmund; Lutz Greb
Journal:  Chem Sci       Date:  2020-08-20       Impact factor: 9.825

Review 8.  Recent developments in the chemistry of non-trigonal pnictogen pincer compounds: from bonding to catalysis.

Authors:  Josh Abbenseth; Jose M Goicoechea
Journal:  Chem Sci       Date:  2020-08-18       Impact factor: 9.825

  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.