| Literature DB >> 29862397 |
Solomon Volodarsky1, Roman Dobrovetsky.
Abstract
In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.Entities:
Year: 2018 PMID: 29862397 DOI: 10.1039/c8cc02423e
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222