Literature DB >> 29847935

Reusable N-Heterocyclic Carbene Complex Catalysts and Beyond: A Perspective on Recycling Strategies.

Wenlong Wang1, Lifeng Cui1, Peng Sun2, Lijun Shi2, Chengtao Yue2, Fuwei Li2.   

Abstract

With the continuous development of N-heterocyclic carbene (NHC) chemistry during the past decade, NHC metal complexes have gained wide applications in the research field of organometallic catalysis. The recycling and reuse of NHC metal complexes, which have undergone continuous expansion and diversification, can enhance their catalytic performance, extend their range of application, and afford new routes to green chemistry. Taking NHC metal complex catalysts as the main topic, this review intends to present a comprehensive study of recycling strategies of organometallic catalysts. By an elaborative summarization and classification of recycling strategies, a clear picture of all available of recycling strategies for organometallic catalysts is presented and the advantages and disadvantages of various recycling strategies for specific reactions are discussed in detail. This review is written with the hope of serving as a modest spur to induce other scientists' further contributions in the fields of catalyst recycling and sustainable catalysis.

Entities:  

Year:  2018        PMID: 29847935     DOI: 10.1021/acs.chemrev.8b00057

Source DB:  PubMed          Journal:  Chem Rev        ISSN: 0009-2665            Impact factor:   60.622


  14 in total

1.  DNP NMR spectroscopy enabled direct characterization of polystyrene-supported catalyst species for synthesis of glycidyl esters by transesterification.

Authors:  Shinji Tanaka; Yumiko Nakajima; Atsuko Ogawa; Takashi Kuragano; Yoshihiro Kon; Masanori Tamura; Kazuhiko Sato; Christophe Copéret
Journal:  Chem Sci       Date:  2022-03-15       Impact factor: 9.969

Review 2.  Combining enyne metathesis with long-established organic transformations: a powerful strategy for the sustainable synthesis of bioactive molecules.

Authors:  Valerian Dragutan; Ileana Dragutan; Albert Demonceau; Lionel Delaude
Journal:  Beilstein J Org Chem       Date:  2020-04-16       Impact factor: 2.883

3.  Catalyst shuttling enabled by a thermoresponsive polymeric ligand: facilitating efficient cross-couplings with continuously recyclable ppm levels of palladium.

Authors:  Erfei Wang; Mao Chen
Journal:  Chem Sci       Date:  2019-07-23       Impact factor: 9.825

4.  Enhancing stability by trapping palladium inside N-heterocyclic carbene-functionalized hypercrosslinked polymers for heterogeneous C-C bond formations.

Authors:  Chengtao Yue; Qi Xing; Peng Sun; Zelun Zhao; Hui Lv; Fuwei Li
Journal:  Nat Commun       Date:  2021-03-25       Impact factor: 14.919

5.  Supramolecular Immobilization of Adamantyl and Carboxylate Modified N-Heterocyclic Carbene Ligand on Cucurbituril Substrates.

Authors:  Hamidou Keita
Journal:  Molecules       Date:  2022-03-03       Impact factor: 4.411

6.  Chemo- and regioselective cross-dehydrogenative coupling reaction of 3-hydroxycarbazoles with arenols catalyzed by a mesoporous silica-supported oxovanadium.

Authors:  Kengo Kasama; Kyohei Kanomata; Yuya Hinami; Karin Mizuno; Yuta Uetake; Toru Amaya; Makoto Sako; Shinobu Takizawa; Hiroaki Sasai; Shuji Akai
Journal:  RSC Adv       Date:  2021-11-02       Impact factor: 4.036

7.  A Fluoroponytailed NHC-Silver Complex Formed from Vinylimidazolium/AgNO3 under Aqueous-Ammoniacal Conditions.

Authors:  Gabriel Partl; Marcus Rauter; Lukas Fliri; Thomas Gelbrich; Christoph Kreutz; Thomas Müller; Volker Kahlenberg; Sven Nerdinger; Herwig Schottenberger
Journal:  Molecules       Date:  2022-06-28       Impact factor: 4.927

8.  Depleting RhoA/Stress Fiber-Organized Fibronectin Matrices on Tumor Cells Non-Autonomously Aggravates Fibroblast-Driven Tumor Cell Growth.

Authors:  Li-Tzu Huang; Chen-Lung Tsai; Shin-Huei Huang; Ming-Min Chang; Wen-Tsan Chang; Li-Hsin Cheng; Hung-Chi Cheng
Journal:  Int J Mol Sci       Date:  2020-11-04       Impact factor: 5.923

9.  Synergy between supported ionic liquid-like phases and immobilized palladium N-heterocyclic carbene-phosphine complexes for the Negishi reaction under flow conditions.

Authors:  Edgar Peris; Raúl Porcar; María Macia; Jesús Alcázar; Eduardo García-Verdugo; Santiago V Luis
Journal:  Beilstein J Org Chem       Date:  2020-08-06       Impact factor: 2.883

10.  Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with π-single bonding character.

Authors:  Zhe Wang; Rikuo Akisaka; Sohshi Yabumoto; Tatsuo Nakagawa; Sayaka Hatano; Manabu Abe
Journal:  Chem Sci       Date:  2020-11-10       Impact factor: 9.825

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