Literature DB >> 29808852

Electrochemical instability of highly fluorinated tetraphenyl borates and syntheses of their respective biphenyls.

Sebastian B Beil1, Sabine Möhle, Patrick Enders, Siegfried R Waldvogel.   

Abstract

Highly fluorinated tetraphenyl borate anions are of importance as weakly coordinating anions in metalorganic reactions. However, at high positive potentials their electrochemical stability in organic solvents is not sufficient. This was investigated by a comprehensive cyclic voltammetry study and can be used synthetically to generate highly fluorinated biphenyls.

Entities:  

Year:  2018        PMID： 29808852     DOI： 10.1039/c8cc02996b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  About the selectivity and reactivity of active nickel electrodes in C-C coupling reactions.

Authors:  Sebastian B Beil; Manuel Breiner; Lara Schulz; Aaron Schüll; Timo Müller; Dieter Schollmeyer; Alexander Bomm; Michael Holtkamp; Uwe Karst; Wolfgang Schade; Siegfried R Waldvogel
Journal:  RSC Adv       Date:  2020-04-08       Impact factor: 3.361

2.  Transition-Metal-Free Oxidative Cross-Coupling of Tetraarylborates to Biaryls Using Organic Oxidants.

Authors:  Carolin Gerleve; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2020-04-24       Impact factor: 15.336
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.