Contamination of heavy metals and isotopic tracing of Pb in surface and profile soils in a polluted farmland from a typical karst area in southern China.

Farmland top soils and soil profiles situated in the karst area of Guilin, Guangxi Zhuang Autonomous Region, southern China, reveal different degrees of heavy metal pollution, both in respect to the lateral as well as the vertical dimension. Pb isotope ratios clearly identify that heavy metal contributions to the soil represent the legacy of former Pb-Zn mining and smelting in the area. Depending upon soil properties, differences in the intensity of the vertical penetration of heavy metal pollution are discernible. Top soil coverage by local farmers provides little remediation. Consequently, hazardous conditions for the regional ecology, for agricultural usage and ultimately for human health remain in place. Based on chemical and isotopic results obtained, more effective remediation strategies need to be developed.